50586-19-1Relevant articles and documents
Simple Stereospecific Syntheses of (E)-1-Chloro(or Bromo)alk-1-enes from Alk-1-ynes via Hydroboration
Masuda, Yuzuru,Hoshi, Masayuki,Arase, Akira
, p. 2723 - 2726 (2007/10/02)
Stereochemically pure (E)-1-chloro(or bromo)alk-1-enes were obtained in sufficiently good yields from alk-1-ynes via hydroboration with dialkylborane followed by reactions with facile reagents; corresponding copper(II) halides, in the presence of a small
SYNTHESIS OF(E) AND (Z) ALKENES VIA PALLADIUM OR NICKEL-CATALYZED REACTION OF VINYL CHLORIDES WITH GRIGNARD REAGENTS.
Ratovelomanana, Victorin,Linstrumelle, Gerard
, p. 179 - 188 (2007/10/02)
We herein described (i) a useful transformation of (E) and (Z) vinyl chlorides into E (and Z) olefins and (ii) an efficient preparation of monoenic alcohols or acetates and its application to insect pheromones.