50606-96-7

Basic information

• Product Name: 4-N-HEPTYLBENZOYL CHLORIDE
• Synonyms: 4-HEPTYLBENZOYL CHLORIDE 99+%;4-n-Heptylbenzoyl chloride, 98+%;4-n-Heptylbenzoylchloride,96%;4-(Hept-1-yl)benzoyl chloride 95+%;Benzoyl chloride,4-heptyl-;P-HEPTYLBENZOYL CHLORIDE;4-heptyl-benzoylchlorid;LABOTEST-BB LT00159029
• CAS NO: 50606-96-7
• Molecular Formula: C₁₄H₁₉ClO
• Molecular Weight: 238.75
• EINECS: 256-648-1
• Product Categories: Benzoic Acids (Building Blocks for Liquid Crystals);Building Blocks for Liquid Crystals;Functional Materials;Acid Halides;Carbonyl Compounds;Organic Building Blocks
• Mol File: 50606-96-7.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 111 °C (0.2 mmHg)
• Flash Point: >230 °F
• Appearance: Clear colorless to brown-orange liquid
• Density: 1.002 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.000296mmHg at 25°C
• Refractive Index: n20/D 1.5218(lit.)
• Sensitive: Moisture Sensitive
• BRN: 2092107
• CAS DataBase Reference: 4-N-HEPTYLBENZOYL CHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-N-HEPTYLBENZOYL CHLORIDE(50606-96-7)
• EPA Substance Registry System: 4-N-HEPTYLBENZOYL CHLORIDE(50606-96-7)

Safety Data

• Hazard Codes: C
• Statements: 34-36/37
• Safety Statements: 26-27-28-36/37/39-45
• RIDADR: UN 3265 8/PG 2
• WGK Germany: 3
• TSCA: Yes
• HazardClass: 8
• PackingGroup: II
• Hazardous Substances Data: 50606-96-7(Hazardous Substances Data)

Usage

Chemical Properties

clear colorless to brown-orange liquid

Uses

4-Heptylbenzoyl chloride was used in the synthesis of 3-O-acyl derivative by reacting with betulinic acid.

InChI:InChI=1/C14H19ClO/c1-2-3-4-5-6-7-12-8-10-13(11-9-12)14(15)16/h8-11H,2-7H2,1H3

Upstream product

• 38350-87-7 4-heptylbenzoic acid 
• 79-37-8 oxalyl dichloride 
• 1078-71-3 heptylbenzene 

Downstream Products

• 61733-47-9 4-n-heptylbenzoic acid 4'-(4-isopropylphenyl)-phenyl ester 
• 64408-98-6 4-Heptyl-thiobenzoic acid S-(4-hexyloxy-phenyl) ester 
• 64408-99-7 4-Heptyl-thiobenzoic acid S-(4-cyano-phenyl) ester 
• 49763-67-9 4-heptylbenzaldehyde 
• 64128-63-8 C₂₈H₃₉NO₂ 
• 37593-03-6 4'-heptylacetophenone 
• 1359983-63-3 C₁₆H₂₃N₃*ClH 
• 1359983-81-5 C₂₁H₃₁N₃O₂ 
• 64328-70-7 ω-Brom-p-(n-heptyl)acetophenon 

Relevant articles and documents

Ni-Catalyzed Aryl Sulfide Synthesis through an Aryl Exchange Reaction

A Ni-catalyzed aryl sulfide synthesis through an aryl exchange reaction between aryl sulfides and a variety of aryl electrophiles was developed. By using 2-pyridyl sulfide as a sulfide donor, this reaction achieved the synthesis of aryl sulfides without using odorous and toxic thiols. The use of a Ni/dcypt catalyst capable of cleaving and forming aryl-S bonds was important for the aryl exchange reaction between 2-pyridyl sulfides and aryl electrophiles, which include aromatic esters, arenol derivatives, and aryl halides. Mechanistic studies revealed that Ni/dcypt can simultaneously undergo oxidative additions of aryl sulfides and aromatic esters, followed by ligand exchange between the generated aryl-Ni-SR and aryl-Ni-OAr species to furnish aryl exchanged compounds.

ALKOXYSILANE COMPOUND, LIQUID CRYSTAL ALIGNING AGENT, LIQUID CRYSTAL ALIGNMENT FILM AND LIQUID CRYSTAL DISPLAY ELEMENT

Provided are an alkoxysilane that is used as a material for liquid crystal alignment films or the like, and a method for producing said alkoxysilane. An alkoxysilane represented by formula (1), wherein a ring structure is linked by an amide bond. (In the formula, Z1, Z2 and Z3 each represent a linear or branched C1-4 hydrocarbon group or the like; Z4 represents H, a methyl group or the like; Y1 represents a single bond, -C(CH3)=CH- or the like; Cy1 represents a phenylene group or the like; Cy2 represents a phenylene group or the like; Z5 represents H, a linear or branched C1-18 hydrocarbon group or the like; a represents an integer of 1-18; m represents 1 or 2; and n represents 0, 1 or 2.)

Highly Efficient Chirality Inductors Based on (5RS,8RS)-trans-5,6,6a,7,8,12b- Hexahydrobenzo[c]phenanthrene-5,8-diol

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