50655-82-8Relevant academic research and scientific papers
On the mechanism of formation of 1-hydroxyalkyl derivatives of mono- and diphosphonic acids
Alovitdinov,Khamrakulov,Khalmukhamedova,Agzamov
, p. 769 - 771 (2007/10/03)
The preparation of (1-hydroxy-1-phenylethyl)phosphonic and 1-hydroxybenzylidene-1,1-diphosphonic acids by phosphorylation of acetophenone and benzoic acid are reported. A new mechanism of phosphorylation of organic acids is proposed for benzoic acid as example.
Phosphorylation of Acetophenone with Phosphorus Trichloride
Khalmukhamedova, M. V.,Agzamov, T. A.,Alovitdinov, A. B.
, p. 360 - 362 (2007/10/03)
The mechanism of acetophenone phosphorylation with phosphorus trichloride to give 1-hydroxy-1-phenylethylphosphonic acid is discussed.A new procedure for synthesizing 1-phenylvinylphosphonic acid by dehydration of 1-hydroxy-1-phenylethylphosphonic acid in the presence of iodine is proposed.
