50715-87-2

Upstream product

• 616-25-1 1-Penten-3-ol 
• 93-55-0 1-phenyl-propan-1-one 
• 199106-77-9 ethyl 2-hydroxy-4-oxo-2-phenylcyclohexanecarboxylate 
• 6738-23-4 2,4-dimethylanisole 
• 71-43-2 benzene 
• 105-67-9 2,4-Xylenol 
• 259822-92-9 ethyl 3-methyl-4-oxo-2-phenylcyclohex-2-enecarboxylate 
• 74-88-4 methyl iodide 

Relevant academic research and scientific papers

Palladium mediated one-pot synthesis of 3-aryl-cyclohexenones and 1,5-diketones from allyl alcohols and aryl ketones

One-pot synthesis of Robinson annulated 3-aryl-cyclohexenones from allyl alcohols and ketones using palladium is reported. Long chain aliphatic or aryl substitutions at the C1 position of allyl alcohol result in the formation of 1,5-diketone products. This simple one-pot method avoids the use of highly electrophilic vinyl ketones.

Studies on alkylation of Hagemann's ester and its derivatives with alkyl halides and Michael acceptors

Alkylation and Michael addition of ethyl 3-methyl-4-oxo-2-phenylcyclohex-2-enecarboxylate (1b) have been studied under basic conditions. Similar reactions with Hagemann's ester (1c) have been carried out using phase transfer catalysts as well as solid supports. The ratio of the C-1 to C-3 alkylated products have been determined. A probable explanation for the regioselectivity observed has been given.

Diprotonation de derives phenoliques. Application a' la preparation de phenyl-3 et de phenyl-4 cyclohexenones

Monocyclic phenols 1-3a (and their methyl ethers) react readily with benzene, in superacid SbF5-HF.In these experiments 4,4 disubstituted cyclohexenones (5, 8 and 11) are the only primary products of the reaction.Their formation is best explain