50917-73-2Relevant articles and documents
Cyclic ketones in spiroannulation
Bjrnstad, Vidar,Undheim, Kjell
, p. 1793 - 1800 (2009)
Conversion of a cyclic carbonyl carbon into a quaternary carbon has been effected by a Wittig-Horner reaction with diethyl (N-benzyliden) aminomethylphosphonate and a subsequent alkylation with a protected vinyl ketone. The product was a substrate for spiroannulation after initial hydrolysis. The reaction sequence was carried out as a one-pot reaction. Copyright Taylor & Francis Group, LLC.
Synthesis of diethyl α-(o-nitroaryl)phosphoglycines via oxidative nucleophilic substitution of hydrogen in nitroarenes
Makosza, Mieczysaw,Sulikowski, Daniel
scheme or table, p. 1666 - 1668 (2010/08/22)
The carbanion of protected diethyl phosphoglycinate adds to nitroarenes in liquid ammonia in ortho position to the nitro group. Subsequent oxidation of the resulting adduct σH with potassium permanganate gave N-protected diethyl α-(o-nitroaryl)phosphoglycinates. Georg Thieme Verlag Stuttgart New York.
1,3-Dipolar cycloaddition of several azomethine ylides to [60]fullerene: Synthesis of derivatives of 2′,5′-dihydro-1′H-pyrrolo[3′,4′:1,2][60]fullerene
Wu, Shi-Hui,Sun, Wei-Quan,Zhang, Dan-Wei,Shu, Lian-He,Wu, Hou-Ming,Xu, Jing-Fei,Lao, Xia-Fei
, p. 1733 - 1738 (2007/10/03)
Imines 1 have been prepared by the condensation of benzaldehyde and corresponding primary amines in which the ester group, phosphonate ester group and depsipeptide are introduced. [60]Fullerene reacts with imines 1 to give the corresponding isomers of fullerene-fused proline derivatives 2 via a process of 1,3-dipolar cycloaddition. 1,3,5-Tris(ethoxycarbonylmethyl)perhydro-1,3,5-triazine 4, which has been prepared by the condensation of ethyl glycinate with paraformaldehyde, depolymerizes thermally to provide an azomethine ylide which reacts with [60]fullerene to afford ethyl 2′,5′-dihydro-1′H-pyrrolo-[3′,4′:1,2][60] fullerene-2′-carboxylate 5. 2-Phenyl-4,5-dihydrooxazol-5-one 6 tautomerizes thermally to form the mesoionic oxazolium 5-oxide 6a, which then, as a cyclic azomethine ylide, combines further with [60]fullerene to give 5′-phenyl-2′H-pyrrolo[3′,4′:1,2][60]fullerene 7 which possesses Cs symmetry.