51116-03-1

Basic information

• Product Name: 2,3-DIBBROME-1-PROPANESULFONIC ACID SODIUM SALT
• Synonyms: 2,3-DIBBROME-1-PROPANESULFONIC ACID SODIUM SALT;Sodium 2,3-dibromopropane-1-sulfonate
• CAS NO: 51116-03-1
• Molecular Formula: C₃H₅Br₂O₃S*Na
• Molecular Weight: 303.934
• Mol File: 51116-03-1.mol

Chemical Properties

• Appearance: /
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 2,3-DIBBROME-1-PROPANESULFONIC ACID SODIUM SALT(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-DIBBROME-1-PROPANESULFONIC ACID SODIUM SALT(51116-03-1)
• EPA Substance Registry System: 2,3-DIBBROME-1-PROPANESULFONIC ACID SODIUM SALT(51116-03-1)

Safety Data

• Hazardous Substances Data: 51116-03-1(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
2,3-Dibromo-1-propanesulfonic acid sodium salt is used as a reagent in organic synthesis for its ability to react with a wide range of organic compounds, facilitating the formation of new chemical entities.
Used in Pharmaceutical Production:
In the pharmaceutical industry, 2,3-Dibromo-1-propanesulfonic acid sodium salt is used as an intermediate in the production of various pharmaceuticals, contributing to the development of new drugs and medicines.
Used in Agrochemical Production:
2,3-DIBBROME-1-PROPANESULFONIC ACID SODIUM SALT is also utilized as an intermediate in the production of agrochemicals, playing a role in the creation of agricultural products that protect and enhance crop yields.
Used as a Catalyst:
2,3-Dibromo-1-propanesulfonic acid sodium salt is used as a catalyst in various chemical reactions due to its strong acidic properties, which can speed up the reaction process and improve efficiency.
Used as a Stabilizer in Polymers:
In the polymer industry, it serves as a stabilizer, enhancing the properties and performance of certain polymers by preventing degradation and improving stability.
Used in Dye Intermediates:
2,3-DIBBROME-1-PROPANESULFONIC ACID SODIUM SALT is used as a dye intermediate, contributing to the production of dyes that are used in various applications, including textiles and other industries.
Used in Surfactant and Emulsifying Agent Manufacture:
2,3-Dibromo-1-propanesulfonic acid sodium salt is utilized in the manufacture of surfactants and emulsifying agents, which are essential in a wide range of industrial and consumer products for their ability to reduce surface tension and stabilize mixtures.

Upstream product

• 2495-39-8 sodium prop-2-ene-1-sulfonate 

Downstream Products

• 189756-89-6 2-bromopropane-1,3-sultone 
• 4076-02-2 unithiol 

Relevant articles and documents

Method for preparing sodium 2,3-dimercapto-1-propanesulfonate

The invention belongs to the technical field of drug synthesis, and in particular relates to a method for preparing sodium 2,3-dimercapto-1-propanesulfonate. With sodium allysulfonate used as a starting material and through a bromination reaction, a sulfhydrylation reaction, a lead salt reaction and a lead removal reaction, high-content sodium 2,3-dimercapto-1-propanesulfonate is obtained by refinement. The total yield is 23.2% and above; especially when zinc dust reduction step is added after hydrolysis, the yield can be greatly increased, the total yield can reach 35-41.5%, and the refined sodium 2,3-dimercapto-1-propanesulfonate content reaches 99% and above. Ethanethioic acid potassium salt is used as a sulphurizing agent and then is hydrolyzed under strong acid conditions, and dilutesulfuric acid is used for lead removal after lead formation. During the whole reaction and treatment process, toxic gas hydrogen sulfide which affects the environment is prevented from being used or generated. Thereby, working conditions are improved, emission of three wastes is reduced, and production efficiency is enhanced.

A kind of improved 2, 3 - dimercapto method for the synthesis of the sodium

The invention belongs to the organic or drug synthesis field and relates to a synthetic method of improved sodium 2,3-dimercaptosulphonate. The adopted technical scheme is as follows: sulfhydrylation reaction is adopted, wherein the PH value of sodium (potassium) bisulfide solution is an important process parameter of the sulfhydrylation reaction. Commercial NaHS solids are dissolved with water, halogenated acids such as concentrated hydrochloric acid and the like are used for neutralizing until the PH value is 6.5-7, and then the NaHS solution is reacted with 2,3-dibromo-1-propanesulfonic acid sodium salt; and besides, high-selectivity environment and condition are provided for the sulfhydrylation reaction of sodium 2,3-dimercaptosulphonate, hydrogen sulfide gas which is highly toxic is not used, and the working condition is improved; and furthermore, hydrogen chloride methanol solution is used for deleading reaction, the hydrogen sulfide gas which is highly toxic and has influence on environment is avoided, and the working condition is improved.

1,3-Dipolar cycloaddition reactions of nitrones to prop-1-ene-1,3-sultone

The reaction of prop-1-ene-1,3-sultone (1) with a variety of nitrones 2 afforded novel [3+2] cycloaddition products 3, 4, and 5 in good yield. Excellent regio- and stereoselectivity were achieved in the cycloaddition reaction with phenylnitrones.

1,3-Dipolar Cycloaddition Reactions of Nitrile Oxides to Prop-1-ene-1,3-sultone

The reaction of prop-1-ene-1,3-sultone 1 with a variety of nitrile oxides 3 afforded novel [3+2] cycloaddition products 4 in good yield. The cycloaddition reaction achieved excellent regioselectivity.

Synthesis and Diels-Alder reactions of prop-1-ene-1,3-sultone, and chemical transformations of the Diels-Alder adducts

A reliable and novel synthetic route for the preparation of prop-1-ene- 1,3-sultone (1) has been developed. An overall yield of 34% could be achieved for this five-step synthesis. The Diels-Alder reactions of 1 with a variety of dienes were investigated for the first time and achieved with good chemical yield and excellent endo-selectivity. The subsequent transformations of the Diels-Alder cycloadducts were also explored.

Synthesis and Diels-Alder reactions of α,β-unsaturated γ-sultone

An efficient synthesis of prop-1-ene 1,3-sultone 1 and its Diels-Alder reactions are reported; ring-opening reactions of the cycloadducts with nucleophiles and transformations to the sultams were also investigated.