51170-34-4Relevant academic research and scientific papers
Nucleophilic Functionalizations of Aniline Derivatives: Aromatic Pummerer Reaction for Umpolung Halogenation and Hydroxylation on Benzene Ring
Bao, Xingping,Yao, Jinzhong,Zhou, Hongwei,Xu, Guangyu
supporting information, p. 5780 - 5782 (2017/11/10)
In this paper, a metal-free protocol of nucleophilic ortho-halogenation and hydroxylation of anilines via an aromatic Pummerer process is reported.
Regioselective synthesis of 2,3,5-trisubstituted indoles from p-sulfinylaniline by dual use of the sulfinyl group
Akai, Shuji,Kawashita, Norihito,Morita, Nobuyoshi,Nakamura, Yuka,Iio, Kiyosei,Kita, Yasuyuki
, p. 75 - 78 (2007/10/03)
A novel and convergent synthesis of 2,3,5-trisubstituted indoles (6) from p-sulfinylaniline (1) is described. The single p-sulfinyl group was repeatedly employed in two ways; viz., the construction of the 2,3-disubstituted indole/indoline skeleton and the
