51274-57-8Relevant academic research and scientific papers
Synthesis of triazenes by using aryl diazonium silica sulfates under mild conditions
Zarei, Amin,Khazdooz, Leila,Aghaei, Hamidreza,Azizi, Ghobad,Chermahini, Alireza Najafi,Hajipour, Abdol R.
, p. 295 - 302 (2013/11/19)
An efficient, fast and straightforward procedure for the synthesis of aryltriazenes is described in the present paper by using aryl diazonium silica sulfates and secondary amines. Using the present method, different kinds of aryl diazonium silica sulfates
Rhodium(III)-catalyzed C-H activation of arenes using a versatile and removable triazene directing Group
Wang, Chengming,Chen, Hu,Wang, Zhaofeng,Chen, Jiean,Huang, Yong
supporting information; experimental part, p. 7242 - 7245 (2012/09/07)
Diverse opportunities: A Rhodium(III)-catalyzed ortho-selective olefination of arenes using a novel triazene as a directing group is reported. This method exhibits substantial post-functionalization synthetic versatility, overcoming a vital limitation in Ca spa 2-H activation/functionalization products: restricted structural diversity. Copyright
Synthesis of Biaryls from Aryltriazenes
Patrick, Timothy B.,Willaredt, Richard P.,DeGonia, David J.
, p. 2232 - 2235 (2007/10/02)
Aryltriazenes react with aromatic solvents in the presence of trifluoroacetic acid to produce biaryls.The mechanism of the reaction involves the formation of arenediazonium trifluoroacetates which lose nitrogen to give mainly aryl radicals.
