51354-18-8

Basic information

• Product Name: DIPHENYL CYANOPHOSPHONATE
• Synonyms: DIPHENYL CYANOPHOSPHONATE
• CAS NO: 51354-18-8
• Molecular Formula: C₁₃H₁₀NO₃P
• Molecular Weight: 259.197161
• Mol File: 51354-18-8.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 362°Cat760mmHg
• Flash Point: 172.7°C
• Appearance: /
• Density: 1.3g/cm³
• Vapor Pressure: 2E-05mmHg at 25°C
• Refractive Index: 1.575
• CAS DataBase Reference: DIPHENYL CYANOPHOSPHONATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIPHENYL CYANOPHOSPHONATE(51354-18-8)
• EPA Substance Registry System: DIPHENYL CYANOPHOSPHONATE(51354-18-8)

Safety Data

• Hazardous Substances Data: 51354-18-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H10NO3P/c14-11-18(15,16-12-7-3-1-4-8-12)17-13-9-5-2-6-10-13/h1-10H

Upstream product

• 151-50-8 potassium cyanide 
• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 143-33-9 sodium cyanide 
• 4712-55-4 diphenyl hydrogen phosphite 
• 506-68-3 bromocyane 
• 2161-16-2 phosphorous acid ethyl ester-diphenyl ester 

Downstream Products

• 1195162-91-4 diphenyl benzyl(cyanocarbonyl)phosphoramidate 
• 21037-12-7 1,3-dibenzylimidazolidine-2,4,5-trione 
• 73708-69-7 benzylcarbamoyl cyanide 
• 1195163-39-3 methyl 2-(cyanocarbonylamino)acetate 
• 1195163-79-1 dimethyl 2,2'-(2,4,5-trioxoimidazolidine-1,3-diyl)diacetate 
• 1195163-18-8 (4-methoxybenzyl)carbamoyl cyanide 
• 16728-56-6 5-phenoxy-pentanenitrile 

Relevant articles and documents

Microwave-assisted solvent-free synthesis of pseudohalophosphates

A rapid, efficient, solvent-free, and catalyst-free procedure has been developed for the synthesis of pseudohalophosphates from phosphorochloridate and sodium (or potassium) pseudohalides under microwave irradiation. Diethyl, diisobutyl, and diphenyl phosphorazidates, phosphorocyanidates, and phosphor(isothiocyanidate)s 2a-2i were prepared in good yields under mild conditions. Copyright

Phase-transfer catalyzed pseudohalogenation of phosphorochloridates

Pseudohalogenation of phosphorochloridates by sodium pseudohalides with different phase transfer catalysts and solvents was optimized. Dialkyl and diaryl phosphorazidates phosphorocyanidates, and phosphor(isotniocyanidate)s were prepared in good yields from phosphorochloridates under two kinds of mild phase-transfer catalyzed conditions respectively.

Synthesis of phosphorocyanidates via phosphorochloridates

Dialkyl phosphorocyanidates (2) were obtained from dialkyl phosphorochloridates (1) in high yield (80-86%) at room temperature in methyl cyanide. Reaction between diethyl phosphorochloridate and potassium cyanide was greatly influenced by the solvents use