5145-99-3Relevant academic research and scientific papers
PROCESS FOR PREPARATION OF ALKYL SULFONE COMPOUNDS
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Page/Page column 6, (2012/05/04)
An object of the present invention is to provide a method for preparation of an alkyl sulfone compound simply and safely with high yield, and an alkyl sulfone compound. The present invention is a method for preparing an alkyl sulfone compound represented by formula (2), comprising: oxidizing an alkyl sulfide compound represented by formula (1) using an oxidizing agent in the presence of a tungstate catalyst: in formula (1), R1 represents a C1-C3 alkyl group, and R2 represents a C3-C5 alkyl group, in formula (2), R1 and R2 are the same alkyl groups as R1 and R2 in formula (1), respectively.
Intermediacy of ion neutral complexes in the fragmentation of short-chain dialkyl sulfides
Filsak,Budzikiewicz
, p. 601 - 610 (2007/10/03)
The main fragmentation processes after electron ionization of butyl methyl and butyl ethyl sulfides are rationalized by the intermediacy of the ion neutral complex [RSH · methylcyclopropane](+·) as demonstrated by extensive labeling and collision activation studies.
Alkyl- and Arylsulfenanilides by Cycloelimination of Propene from N-Aryl-S-isopropyl-sulfimides
Claus, Peter K.,Silbernagel, Waltraud,Franek, Walter,Rieder, Werner
, p. 841 - 850 (2007/10/02)
A series of N-aryl-S-isopropyl-S-alkyl- or aryl-sulfimides has been prepared and transformed into alkyl- or arylsulfenanilides, respectively, by thermal cycloelimination of propene. - Keywords: Sulfimides; Sulfenanilides; Thermolysis; Cycloelimination.
