514805-23-3Relevant academic research and scientific papers
Ruthenium-Catalyzed 1,6-Aromatic Enamide-Silylalkyne Cycloisomerization: Approach to 2,3-Disubstituted Indoles
Takamoto, Kohei,Ohno, Shohei,Hyogo, Norimichi,Fujioka, Hiromichi,Arisawa, Mitsuhiro
, p. 8733 - 8742 (2017)
Cycloisomerization is an atom economic procedure that converts dienes and enynes into cyclic molecules. To date, cycloisomerization between enamides and silylalkynes has not been explored. We found that N-acyl-N-vinyl-2-silylalkynylaniline derivatives und
Conjugate additions of o-iodoanilines and methyl anthranilates to acetylenic sulfones. A new route to quinolones including first syntheses of two alkaloids from the medicinal herb Ruta chalepensis
Back, Thomas G.,Parvez, Masood,Wulff, Jeremy E.
, p. 2223 - 2233 (2007/10/03)
A novel synthesis of 2-substituted 4-quinolones was developed on the basis of the conjugate additions of appropriately ortho-substituted anilines to acetylenic sulfones followed by intramolecular acylation of the corresponding sulfone-stabilized anions. C
