51581-40-9

Basic information

• Product Name: 3-PYRIDYL DIETHYLCARBAMATE
• Synonyms: 3-PYRIDYL DIETHYLCARBAMATE
• CAS NO: 51581-40-9
• Molecular Formula: C₁₀H₁₄N₂O₂
• Molecular Weight: 194.23
• Product Categories: pharmacetical;Aromatics;Heterocycles
• Mol File: 51581-40-9.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 290.6 °C at 760 mmHg
• Flash Point: 129.6 °C
• Appearance: /
• Density: 1.096 g/cm³
• Vapor Pressure: 0.00204mmHg at 25°C
• Refractive Index: 1.513
• Storage Temp.: Refrigerator
• Solubility: Chloroform (Slightly), Methanol (Slightly)
• CAS DataBase Reference: 3-PYRIDYL DIETHYLCARBAMATE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-PYRIDYL DIETHYLCARBAMATE(51581-40-9)
• EPA Substance Registry System: 3-PYRIDYL DIETHYLCARBAMATE(51581-40-9)

Safety Data

• Hazardous Substances Data: 51581-40-9(Hazardous Substances Data)

Usage

Chemical Properties

Colourless Oil

Uses

3-Pyridyl Diethylcarbamate (cas# 51581-40-9) is a compound useful in organic synthesis.

InChI:InChI=1/C10H14N2O2/c1-3-12(4-2)10(13)14-9-6-5-7-11-8-9/h5-8H,3-4H2,1-2H3

Upstream product

• 109-00-2 3-HYDROXYPYRIDINE 
• 88-10-8 N,N-diethylcarbamyl chloride 
• 79-44-7 N,N-Dimethylcarbamoyl chloride 

Downstream Products

• 40247-40-3 5,8-endoxo-5,8-dihydroisoquinoline 
• 52334-53-9 4-amino-3-hydroxy pyridine 
• 28856-77-1 3-phenylthiopyridine 
• 33399-48-3 4-(phenylthio)pyridine 
• 142222-57-9 N-Cyclohexyl-N'-(3-hydroxy-pyridin-4-yl)-N-methyl-formamidine 
• 143164-02-7 N-Benzyl-N'-(3-hydroxy-pyridin-4-yl)-N-methyl-formamidine 
• 141811-99-6 4-Phenylsulfanyl-pyridine-2-carboxylic acid diethylamide 
• 142222-62-6 Phenyl-carbamic acid 4-(dimethylamino-methyleneamino)-pyridin-3-yl ester 
• 141811-98-5 C₃₀H₂₆N₂O₂ 
• 142222-90-0 Dimethyl-carbamic acid 4-[(cyclohexyl-methyl-amino)-methyleneamino]-pyridin-3-yl ester 
• 142222-92-2 Dimethyl-carbamic acid 4-[(benzyl-methyl-amino)-methyleneamino]-pyridin-3-yl ester 
• 4373-67-5 3-(3-methoxyphenyl)pyridine 
• 4423-09-0 4-(3-pyridyl)toluene 
• 5958-02-1 3-(4-methoxyphenyl)pyridine 

Relevant articles and documents

N -Arylation of (hetero)arylamines using aryl sulfamates and carbamates via C-O bond activation enabled by a reusable and durable nickel(0) catalyst

An effective and general aryl amination protocol has been developed using a magnetically recoverable Ni(0) based nanocatalyst. This new stable catalyst was prepared on Fe3O4@SiO2 modified by EDTA and investigated by FT-IR, EDX, TEM, XRD, DLS, FE-SEM, XPS, NMR, TGA, VSM, ICP and elemental analysis techniques. The reaction proceeded via carbon-oxygen bond cleavage of (hetero)aryl carbamates and sulfamates under simple and mild conditions without the use of any external ligands. This method demonstrated functional group tolerance in the N-arylation of various nitrogen-containing compounds as well as aliphatic amines, anilines, pyrroles, pyrazoles, imidazoles, indoles, and indazoles with good to excellent yields. Furthermore, the catalyst could be easily recovered by using an external magnetic field and directly reused at least six times without notable reduction in its activity. This journal is

Combined directed ortho metalation-halogen dance (HD) synthetic strategies. HD-anionic ortho fries rearrangement and double HD sequences

A general and efficient directed ortho metalation (DoM)-halogen dance (HD)-electrophile quench sequence for the synthesis of trisubstituted pyridyl O-carbamates is described. A second HD sequence furnishes highly functionalized tetrasubstituted pyridines.

Synthesis of two conformationally constrained analogues of the minor tobacco alkaloid anabasine.

The anabasine analogues spiro[4-azaindan-1,2'-piperidine] (7) and spiro[6-azaindan-1,2'-piperidine] (8) have been prepared. A series of palladium-catalyzed reactions, where an intramolecular cyclization constituted a key reaction, were utilized for the pr