5178-04-1

Upstream product

• 186581-53-3 diazomethane 
• 3806-42-6 5-benzylidene-2-thioxothiazolidin-4-one 
• 78636-81-4 C₁₀H₆NOS₂^(1-) 
• 74-88-4 methyl iodide 
• 77-78-1 dimethyl sulfate 
• 75-15-0 carbon disulfide 
• 100-52-7 benzaldehyde 
• 105-39-5 chloroacetic acid ethyl ester 
• 74-89-5 methylamine 
• 7223-30-5 3-phenyl-propynoic acid amide 
• 63906-52-5 thiocyanatoacetic acid, Na-salt 
• 556-61-6 methyl thioisocyanate 
• 34705-89-0 5-benzylidenerhodanine sodium 
• 72425-49-1 Potassium; 4-oxo-5-[1-phenyl-meth-(E)-ylidene]-4,5-dihydro-thiazole-2-thiolate 

Downstream Products

• 85504-17-2 3-methyl-5-[(Z)-phenylmethylidene]-1,3-thiazolidine-2,4-dione 
• 18331-37-8 diethyl (3-methyl-2-thiono-4-thiazolidinon-5-yl) benzyl phosphonate 
• 102469-25-0 3-methyl-5-(naphthalen-1-yl-phenyl-methyl)-2-thioxo-thiazolidin-4-one 
• 32723-32-3 5-benzylidene-3-methyl-thiazolidine-2,4-dithione 
• 138696-28-3 5-Benzyliden-3-methyl-4-oxothiazolidin-2-thion-S-oxid 
• 5740-34-1 3-phenyl-2-sulfanylpropenoic acid 

Relevant academic research and scientific papers

1-butyl-3-methyl imidazolium acetate catalyzed synthesis of N-substituted-5-arylidene-rhodanines

A direct method for the synthesis of N-substituted-5-arylidene-rhodanines has been reported in high yield via [bmim]OAc-catalyzed one-pot four-component domino Knoevenagel condensation of primary amine, carbon disulfide, ethyl chloroacetate, and aromatic

Reaction of crystals of 5-benzylidenerhodanine and its diethylammonium salt with diazomethane

The reaction of crystalline desmotropic forms of 5-benzylidenerhodanine and its diethylammoium salt and crystal solvates with gaseous diazomethane was studied. Hydrogen bonds do not shield the reaction centers of the ambident triad and exert no effect on

POTASSIUM FLUORIDE ON ALUMINA: CONDENSATION OF 3-METHYL-2-THIONO-4-THIAZOLIDINONE WITH ALDEHYDES. SYNTHESIS OF α-THIOACRYLIC ACIDS AND PHOSPHONOTHIONOTHIAZOLIDINONES

3-Methyl-2-thiono-4-thiazolidinone and aromatic aldehydes adsorbed on potassium fluoride on alumina gave under microwave irradiation 5-arylidene-3-methyl-2-thiono-4-thiazolidinones in 70percent to 90percent yield.These compounds can be cleaved with sodium

REACTIVITY AND TAUTOMERISM OF AZOLIDINES. XLII. ALKYLATION OF THE ALKALI-METAL SALTS OF 5-BENZYLIDENERHODANINE IN THE SOLID PHASE.

The effect of the counterion of the "leaving" group in the alkylating agent on the direction of alkylation in the alkali-metal salts of 5-benzylidenerhodanine in the solid phase was investigated.It was shown that the ratio of the isomeric products from alkylation at the N and S atoms varies with variation of the counterion and the substituted group in accordance with the principle of hard and soft acids and bases and increases in the series Li, Na, K, Cs.

REACTIVITY AND TAUTOMERISM OF AZOLIDINES. XXXVII. EFFECT OF THE NATURE OF THE COUNTERION ON THE DUAL REACTIVITY OF 5-BENZYLIDENERHODANINE DURING METHYLATION

The effect of the nature of the cation in the salts of 5-benzylidenerhodanine in various solvents on the ratio of the constants for alkylation at the S and N centers of 5-benzylidenerhodanine was demonstrated.The rate constants for the reaction of the S and N centers in the ion and ion pair were determined.

REACTIVITY AND TAUTOMERISM OF AZOLIDINES. XXXII. THE EFFECT OF THE NATURE OF THE SOLVENT ON THE DUAL REACTIVITY OF 5-BENZYLIDENERHODANINE IN METHYLATION

The effect of the nature of the solvent on the dual reactivity of 5-benzylidenerhodanine in methylation was investigated.A correlation was obtained between the ratio of the rate constants for the reaction at the N and S centers of the substrate and the polarity of the solvent.Proposals are made concerning the mechanism of solvation of the ambident centers in 5-benzylidenerhodanine.