52039-22-2Relevant academic research and scientific papers
Preparation of Amino(diethoxyphosphoryl)acetic Esters. Catalytic Hydrogenation of Diazo Compounds to Amines
Shiraki, Chihiro,Saito, Hiromitsu,Takahashi, Keiichi,Urakawa, Chikahiro,Hirata, Tadashi
, p. 399 - 401 (2007/10/02)
tert-Butyl amino(diethoxyphosphoryl)acetate (2a) is prepared on a multigram scale from tert-butyl diethoxyphosphorylacetate (1a) in a facile two-step synthesis.The method involves the formation of diazo derivative 4 and subsequent catalytic hydrogenation.Compound 2a is also synthesized by reduction of the oxime derivative 3.Direct amination of diethoxyphosphorylacetic esters with chloramine gives other types of esters 2b-e in addition to the tert-butyl ester 2a.
O-(DIPHENYLPHOSPHINYL)HYDROXYLAMINE: A NEW REAGENT FOR ELECTROPHILIC C-AMINATION
Colvin, Ernest W.,Kirby, Gordon W.,Wilson, Arthur C.
, p. 3835 - 3836 (2007/10/02)
O-(Diphenylphosphinyl)hydroxylamine efficiently aminates a variety of stabilised carbanions and certain Grignard reagents.
