52072-12-5Relevant articles and documents
Direct α-acyloxylation of organic sulfides with the hypervalent (diacyloxyiodo)benzene/tetra-n-butylammonium bromide (TBAB) reagent combination
Zhu, Dan,Chang, Denghu,Gan, Shaoyan,Shi, Lei
, p. 27983 - 27987 (2016/04/04)
A novel metal-free approach to directly synthesize α-acyloxy sulfides from readily available alkyl sulfides utilizing the hypervalent (diacyloxyiodo)benzene and TBAB reagent combination is reported. This transformation is characterized by its broad substrate scope in moderate to excellent yields, convenient operating conditions and outstanding functional group tolerance.
CONVERSIONS OF ALLYL ARYL SULFOXIDES UNDER PUMMERER REARRANGEMENT CONDITIONS
Fedorov, N. V.,Shevchenko, M. V.,Anisimov, A. V.,Viktorova, E. A.
, p. 624 - 626 (2007/10/02)
In the presence of acetic acid, allyl phenyl sulfoxides forms α-acetoxyallyl phenyl sulfides and 2-acetoxymethyl-2,3-dihydrobenzothiophene; under the same conditions allyl 1-naphthyl sulfoxide gives 2-methyl-2,3-dihydronaphtho-thiophenoxide.