52175-06-1Relevant academic research and scientific papers
Kinetic Study on the Alkaline Hydrolysis of Some Tetracoordinate PV Esters of 2,4-Dinitrophenol
Cevasco, Giorgio,Thea, Sergio
, p. 1103 - 1106 (2007/10/02)
The alkaline hydrolysis of 2,4-dinitrophenyl esters of benzylphosphinic, benzylphosphonic and benzylphosphonamidic acid does not proceed through a carbanion-promoted dissociative mechanism, a possible alternative pathway to the usual SN2(P) process; this is a further indication of the clear preference for associative displacement at phosphorous.
PHOSPHONIC SYSTEMS. 4. PREPARATION OF TETRAETHYLALKYLPHOSPHONIC DIAMIDES
Jongh, C. P. de,Zwierzak, A.,Modro, T.A.
, p. 205 - 209 (2007/10/02)
The preparation of N,N,N',N'-tetraethylalkylphosphonic diamides, R-P(O)(NEt2)2 from the corresponding haloalkanes and the lithium derivative of bis(diethylamino)phosphorous acid is reported. Keywords: Alkylphosphonodiamidates; diamidophosphite ion as a nucleophile in SN2 reaction:
