52567-52-9

Upstream product

• 37384-69-3 3-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-propenoic acid 
• 176324-33-7 ethyl 2-ethoxycarbonyl-3-(2,6,6-trimethyl-2-cyclohexenyl)-propanoate 
• 24739-70-6 cyclogeranyl p-toluenesulfonate 
• 126456-65-3 ethyl 3-(2,6,6-trimethyl-2-cyclohexenyl)-2-propenoate 
• 14505-74-9 α-cyclocitral 
• 6627-74-3 (+/-)-α-cyclogeraniol 
• 176324-34-8 ethyl 3-(2,6,6-trimethyl-2-cyclohexenyl)-propanoate 
• 24190-34-9 4-[(1S)-2,6,6-trimethylcyclohex-2-en-1-yl]butan-2-one 
• 14398-36-8 (3E)-4-[(S)-2,6,6-trimethylcyclohex-2-enyl]but-3-en-2-one 

Downstream Products

• 52567-53-0 (-)-Dihydro-α-cyclocitryliden-essigsaeuremethylester 

Relevant academic research and scientific papers

Raney nickel: An efficient reagent to achieve the chemoselective hydrogenation of α,β-unsaturated carbonyl compounds

Raney Nickel is an effective reagent to achieve the chemoselective reduction of conjugated olefins in σ,β-unsaturated carbonyl compounds that also contain isolated double bonds. Its use is also compatible with a variety of other functional groups.

Model insect antifeedants. Synthesis of azadiradione fragments through acyl radicals cyclizations and stannane coupling reactions

A diastereoselective and versatile synthesis of the model insect antifeedant 16 related to azadiradione has been achieved in nine steps starting from α-cyclocitral 1. The key steps involve intramolecular alkene addition of an acyl radical and a Stille coupling reaction of a vinyl iodide with a stannylfuran.