14398-36-8Relevant articles and documents
The Synthesis of Optically Active Enriched (+)-(6R)-α-Ionone
Pfander, Hanspeter,Semadeni, Pascal A.
, p. 145 - 151 (1995)
Starting with the readily available (-)-(S)-4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-one (2) an optically active enriched sample of (+)-(6R)-α-ionone (1) (85percent enantiomeric excess) was synthesized.
Controlled release of encapsulated bioactive volatiles by rupture of the capsule wall through the light-induced generation of a gas
Paret, Nicolas,Trachsel, Alain,Berthier, Damien L.,Herrmann, Andreas
supporting information, p. 2275 - 2279 (2015/02/19)
The encapsulation of photolabile 2-oxoacetates in core-shell microcapsules allows the light-induced, controlled release of bioactive compounds. On irradiation with UVA light these compounds degrade to generate an overpressure of gas inside the capsules, which expands or breaks the capsule wall. Headspace measurements confirmed the light-induced formation of CO and CO2 and the successful release of the bioactive compound, while optical microscopy demonstrated the formation of gas bubbles, the cleavage of the capsule wall, and the leakage of the oil phase out of the capsule. The efficiency of the delivery system depends on the structure of the 2-oxoacetate, the quantity used with respect to the thickness of the capsule wall, and the intensity of the irradiating UVA light.
ω-Sulfonic-perfluoroalkylated poly(styrene-maleic anhydride)/silica hybridized nanocomposite as a new kind of solid acid catalyst
Lin, Zhenghuan,Huang, Limei,Ling, Qidan,Chen, Hong,Zhao, Chengxue
, p. 73 - 79 (2013/01/14)
A new kind of ω-sulfonic-perfluoroalkylated poly(styrene-maleic anhydride)/silica hybrid nanocomposite FSMA/SiO2 has been synthesized under mild conditions by perfluoroalkylation of styrene-maleic anhydride copolymer (SMA) with ω-fluorosulfonylperfluorodiacyl peroxides (SFAP), and followed in turn by aminolysis using (3-aminopropyl)triethoxysilane (APTES), alkali hydrolysis, gelation with tetraethoxysilane (TEOS) and finally acidification. The hybrid solid acid FSMA/SiO2 with terminal perfluoroalkylsulfonic and carboxyl groups was characterized by FTIR, SEM, TEM, TGA, XPS, EDX, acidimetry and nitrogen sorption technique. Its pore structure, acid strength and acid amount were easily modulated by controlling the gelation and perfluoroalkylation conditions. The catalytic activity and selectivity, as well as reusability of FSMA/SiO2 were tested in three important reactions, namely, cyclization of pseudoionone, condensation of indole and esterification of benzoic acid. Owing to the higher exchange capacity than that of Nafion/SiO2, and the stronger acidity than that of Amberlyst-15, the nanocomposite FSMA/SiO2 showed higher activity and selectivity than these commercial solid acids in the reactions.