5274-38-4Relevant academic research and scientific papers
Hydroperoxo double hydrogen bonding: Stabilization of hydroperoxo complexes exemplified by triphenylsilicon and triphenylgermanium hydroperoxides
Churakov, Andrei V.,Grishanov, Dmitry A.,Lev, Ovadia,Medvedev, Alexander G.,Mikhaylov, Alexey A.,Prikhodchenko, Petr V.
, p. 1922 - 1928 (2020/03/23)
Triphenyl silicon hydroperoxide and its isostructural germanium complex were characterized by single crystal X-ray analysis revealing H-bonding of two triphenylhydroperoxocomplexes, with each hydroperoxo ligand acting as a hydrogen donor and a hydrogen ac
Reactions of titanium alcoholates Ti(OR)4 (R = n-Bu, t-Bu) with tertiary organic and organometallic hydroperoxides
Stepovik,Gulenova
, p. 235 - 244 (2008/02/09)
tert-Butyl and cumyl hydroperoxides in the reactions with Ti(OR) 4 are reduced to alcohols with the evolution of oxygen via formation of titanium-containing peroxides and trioxides. The pathways of the reactions of Ti(OR)4 with triphenylelement hydroperoxides R3EOOH (E = C, Si, Ge) depend on element E and on the structure of R; the reactions involve the rearrangement of the peroxides, and with (n-BuO)4Ti the alkoxy group is oxidized either with preservation or with breakdown of the hydrocarbon skeleton. Pleiades Publishing, Inc., 2006.
