52816-35-0Relevant academic research and scientific papers
Novel generation of azomethine imines from α-silylnitrosamines by 1,4- silatropic shift and their cycloaddition
Washizuka, Ken-Ichi,Nagai, Keiko,Minakata, Satoshi,Ryu, Ilhyong,Komatsu, Mitsuo
, p. 8849 - 8853 (2007/10/03)
Novel and facile generation of azomethine imines from α- silylnitrosamines and subsequent cycloaddition with dipolarophiles leading to a variety of pyrazole derivatives have been developed. The key to the reaction is a 1,4-silatropic shift caused by stron
Benzoyl phenyl 1-methylpyrazoles. Synthesis, characterization, and spectra
Kano, Kunio,Scarpetti, David,Warner, John C.,Anselme, Jean-Pierre,Springer, James H.,Arison, Byron H.
, p. 2211 - 2219 (2007/10/02)
The synthesis and unequivocal characterization of all six isomers of benzoyl phenyl 1-methylpyrazole (2) are described.The isomer of 2 isolated as one of the products of the reaction of 1,1-dimethyl-1-phenacylhydrazinium bromide (1) with base was shown to be only previously reported isomer, 5-benzoyl-3-phenyl-1-methylpyrazole (2b).
