52826-42-3Relevant academic research and scientific papers
Facile route for the synthesis of triosmium and triruthenium isocyanide complexes
Lu, Kuang-Lieh,Chen, Chi-Cheng,Lin, Yen-Wen,Hong, Fung-E,Gau, Han-Mou,et al.
, p. 263 - 267 (1993)
The osmium isocyanide complexes Os3(CO)11(CNR) (1a, R = Pr; 1b, R = iPr; 1c, R = CH2Ph; 1d, R = Ph) are synthesized in high yields by reaction of Os3(CO)12 with phosphine imides via a deoxygenation mechanism.These complexes react with an additi
THE SYNTHESIS AND CHARACTERIZATION OF MIXED (ALKYLAMINO) AND (ARYLAMINO)PHENYLPHOSPHONIUM COMPOUNDS
Fuente, German F. de la,Huheey, James E.
, p. 23 - 36 (2007/10/02)
The syntheses of alkyl and aryl-substituted tetrakis(amino)phenylphosphonium compounds of type (RNH)4-n(C6H5)nPX, where R = n-C3H7 (1), i-C3H7 (2), n-C4H9 (3), s-C4H9 (4), n-C6H13 (5), c-C6H11 (6), C6H5CH2 (7) and C6H5 (8), and where
Alkylation et acylation de la triphenylphosphinimine N-lithiee
Cristau, Henri-Jean,Kadoura, Jumaah,Chiche, Laurent,Torreilles, Eliane
, p. 515 - 520 (2007/10/02)
A new synthetic approach to primary and secondary amines using N-lithiated triphenylphosphinimine is reported.This key reagent, accessible in two steps from dibromortiphenylphosphorane and ammonia, when treated with electrophiles yields N-substituted triphenylphosphinimine derivatives.These can react to give N-mono or disubstituted triphenylphosphonium salts which upon hydrolysis lead to the corresponding primary and secondary amines.
L'AZA-YLURE N-LITHIE (C6H5)3P=NLi, REACTIF D'AMINATION
Cristau, H. J.,Chiche, L.,Kadoura, J.,Torreilles, E.
, p. 3931 - 3934 (2007/10/02)
The preparation of the lithiated aza-ylide 3 has been improved and its one-pot reactivity toward alkyl and acyl halides to give amino-phosphonium salts and accordingly amines is described.
