52867-19-3

Basic information

• Product Name: diphenyl-N-(p-toluenesulfonyl)selenimide
• Synonyms: diphenyl-N-(p-toluenesulfonyl)selenimide
• CAS NO: 52867-19-3
• Molecular Weight: 402.375
• Mol File: 52867-19-3.mol

Chemical Properties

• CAS DataBase Reference: diphenyl-N-(p-toluenesulfonyl)selenimide(CAS DataBase Reference)
• NIST Chemistry Reference: diphenyl-N-(p-toluenesulfonyl)selenimide(52867-19-3)
• EPA Substance Registry System: diphenyl-N-(p-toluenesulfonyl)selenimide(52867-19-3)

Safety Data

• Hazardous Substances Data: 52867-19-3(Hazardous Substances Data)

Upstream product

• 1132-39-4 diphenylselenide 
• 127-65-1 chloroamine-T 
• 15804-14-5 Diphenylselenium dimethylate 
• 70-55-3 toluene-4-sulfonamide 
• 2217-81-4 diphenylselenium dichloride 

Downstream Products

• 1132-39-4 diphenylselenide 
• 70-55-3 toluene-4-sulfonamide 
• 7304-91-8 diphenylselenoxide 
• 51608-60-7 N-(benzylidene)-p-methylbenzenesulfonamide 
• 882-33-7 diphenyldisulfane 
• 36176-90-6 N-(4-bromobenzylidene)-4-methylbenzenesulfonamide 
• 34283-30-2 3,5-diamino-1,2,4-thiadiazole 
• 150-60-7 dibenzyl disulphide 
• 4115-15-5 3,5-diphenyl-[1,2,4]thiadiazole 
• 14674-40-9 N-(4-(dimethylamino)benzylidene)-4-methylbenzenesulfonamide 
• 61449-37-4 2,4-diphenyl-3,5-bis(phenylimino)-1,2,4-thiadiazolidine 
• 4083-64-1 Tosyl isocyanate 
• 56593-11-4 2-(Diphenyl-λ⁴-selanylidene)-malononitrile 
• 13256-69-4 1-p-tosyl-3-(2-chlorophenyl)urea 

Relevant articles and documents

Structural and Nuclear Magnetic Resonance Studies of short Selenium - Nitrogen Bonds

SeCl4 reacts with Ph3P=NSiMe3 (2) by elimination of SiMe3Cl to form Ph3P=NSeCl3 (3), which is converted to (Ph3P=N)2SeCl2 (4) by a further mole of (2).Compound (4) may also be prepared from (2) and SeOCl2 or Se2Cl2; (4) reacts with SbCl5 to from (Ph3P=N)

PREPARATION AND REACTION OF N-TOSYL- AND N-ACYLSELENILIMINES

N-Tosyl-Se,Se-diphenylselenilimines (Ia, hydrate state (Ib) of Ia), N-tosyl-Se-methyl-Se-phenylselenilimines (Ic), N-tosyl-Se,Se-dialkylselenilimines (Id-f), N-acyl-Se-aryl-Se-phenyl-selenilimines (IIa-e) and N-acyl-Se,Se-dibenzylselenilimine (IIf) were prepared.The pyrolyses of selenilimines (Ia, d, e, IIa-e) proceeded more readily than those of the corresponding sulfur derivatives.The pyrolyses of N-acyl-Se-aryl-Se-phenylselenilimines gave the corresponding isocyanates in good yields after treatment of the reaction mixture with aniline, together with aryl phenyl selenide.A ki netic study revealed that the rate of pyrolysis of N-benzoyl-Se,Se-diphenylselenilimine (IIa) was 300 times faster than that of the corresponding sulfilimine.The activation enthalpy and entropy were ΔH* = 32.1 kcal/mol and ΔS* = 1.2 e.u. respectively for Ph2Se -> NCOPh.Oxidations of N-tosyl- and N-benzoyl-Se,Se-diphenylselenilimine were carried out with hydrogen peroxide or potassium permanganate to obtain the corresponding selenoxides or selenones, respectively.Hydrolysis of N-tosyl- and N-benzoyl-Se,Se-diphenylselenilimines also took place more readily than that of the corresponding sulfilimines and the selenoxides and the amides were obtained in good yields at room temperature.When N-tosyl-Se,Se-pentamethyleneselenilimine (Ie) was treted with conc. sulfuric acid, a selenurane, Se-hydroxy-Se-(hydroxysulfoxy)selenane (III) was obtained in a high yield.