52894-43-6

Usage

InChI:InChI=1/C7H10S3/c1-3-5-9-7(8)10-6-4-2/h3-4H,1-2,5-6H2

Upstream product

• 556-56-9 allyl iodid 
• 534-18-9 sodium trithiocarbonate 
• 75-15-0 carbon disulfide 
• 107-05-1 3-chloroprop-1-ene 
• 106-95-6 allyl bromide 
• 4873-09-0 allyl tosylate 
• 584-10-1 potassium trithiocarbonate 
• 870-23-5 prop-2-ene-1-thiol 

Downstream Products

• 870-23-5 prop-2-ene-1-thiol 
• 1147550-11-5 ammonium thiocyanate 

Relevant academic research and scientific papers

A convenient one-pot method for the synthesis of symmetrical dialkyl trithiocarbonates using NH4OAc under mild neutral conditions

A facial, new, one-pot method for the preparation of symmetrical organic trithiocarbonates from various alkyl halides and carbon disulfide is described. This is a convenient, clean, and mild procedure, which involves the use of the neutral, nontoxic, commercially available, and inexpensive reagent NH4OAc in the preparation of the trithiocarbonate ion from carbon disulfide.

Superbasic system CsOH/DMSO as a reagent for a fast one-step synthesis of symmetrical dialkyl trithiocarbonates

Symmetrical dialkyl trithiocarbonates were readily synthesized in excellent yields by one-step reaction of carbon disulfide and various alkyl halides under mild reaction conditions in the presence of cesium hydroxide as a super basic system. This method provides a synthesis of symmetrical dialkyl trithiocarbonates in short reaction times without the use of highly toxic starting materials.

An Efficient and Straightforward Access to Symmetrical Dialkyl Trithiocarbonates Using a Basic Task-Specific Ionic Liquid and Carbon Disulfide

We report an efficient one-pot route for the synthesis of symmetrical dialkyl trithiocarbonates from alkyl halides using carbon disulfide and a basic ionic liquid 1,1′-bis-methyl-3, 3-methylene-bisimidazolium dihydroxide as a reagent and phase-transfer catalyst.

An efficient one-pot approach to the synthesis of symmetric trithiocarbonates from carbon disulfide and alkyl halides using imidazole

A novel method is reported for the synthesis of symmetric dialkyl and cyclic (5, 6 and 7 member) trithiocarbonates from alkyl halides and carbon disulfide in the presence of imidazole and water in DMSO under mild reaction conditions. Imidazole is used as an inexpensive, non-toxic and readily available catalyst in this procedure.

K3PO4-mediated one-pot synthesis of symmetrical trithiocarbonates

A new procedure has been developed for synthesis of symmetrical trithiocarbonates by one-pot reaction of carbon disulfide, and various alkyl halides in dimethylformamide using K3PO4 as an inexpensive and effective reagent.

TBAH-catalyzed one-pot synthesis of symmetrical trithiocarbonates from alkyl halides and carbon disulfide under neat aqueous conditions

A novel and efficient, tetra-n-butylammonium hydroxide catalyzed, one-pot protocol has been developed for the synthesis of symmetrical trithiocarbonates from alkyl halides and carbon disulfide under neat aqueous conditions. Georg Thieme Verlag Stuttgart - New York.

A novel one-step synthesis of symmetrical dialkyl trithiocarbonates in the presence of phase-transfer catalysis

Symmetrical trithiocarbonates were directly obtained, in moderate to excellent isolated yields, by the reaction of various primary, secondary, allylic and benzylic halides or alkyl tosylates with a suspension of granulated KOH and alumina in CS2 under phase-transfer catalysis. In this manner, cyclic trithiocarbonates such as 1,3-dithiolane-2-thione can also be prepared without formation of any polymeric by-products.

An efficient, one-pot synthesis of trithiocarbonates from alcoholic tosylates using the Cs2CO3/CS2 system

A single-step novel protocol for the preparation of symmetrical trithiocarbonates from a corresponding variety of primary, secondary, and tertiary alcoholic tosylates using the Cs2CO3/CS 2 system, was developed. This protocol is mild and more efficient than the reported methods.

A facile KF/Al2O3-mediated, one-pot synthesis of symmetrical trithiocarbonates from alkyl halides and carbon disulfide

A facile, efficient, and convenient method has been developed for the one-pot synthesis of symmetrical trithiocarbonates from carbon disulfide and various alkyl halides in the presence of KF/Al2O3 in DMF at room temperature. Copyright

Basic Al2O3 as an efficient heterogeneous reagent for the synthesis of symmerical dialkyl trithiocarbonates

This work deals with reaction of alkyl halides with carbon disulfide in the presence of basic alumina as heterogeneous and reusable reagent. It afforded symmetrical dialkyl trithiocarbonate in moderate to excellent isolated yields. Reaction of 1,2-dichloro ethane with carbon disulfide also proceeded in a similar manner to give a five-membered cyclic trithiocarbonate without formation of any polymeric by-product. Copyright Taylor & Francis Group, LLC.