530740-48-8Relevant academic research and scientific papers
Chiral amplification in the transcription of supramolecular helicity into a polymer backbone
Wilson, Andrew J.,Masuda, Mitsutoshi,Sijbesma, Rint P.,Meijer
, p. 2275 - 2279 (2005)
(Figure Presented) A chiral supramolecular "sergeant" as the structure-directing agent affects the backbone stereochemistry during polymerization of the achiral "soldier" monomers. The polymer obtained shows preferred helical folding despite its mixed mic
Photoinitiated Polymerization of Columnar Stacks of Self-Assembled Trialkyl-1,3,5-benzenetricarboxamide Derivatives
Masuda, Mitsutoshi,Jonkheijm, Pascal,Sijbesma, Rint P.,Meijer
, p. 15935 - 15940 (2007/10/03)
A disk-shaped molecule, N-(5-sorbyl-pentyl)-N′,N″ -di(n-octyl)benzene-1,3,5-tricarboxamide (1), has been synthesized and assembled into a columnar stack in cyclohexane. Using a photoinitiated process, we polymerized monomer 1 in its self-assembled state a
