38588-64-6Relevant academic research and scientific papers
Silica-Mediated Monohydrolysis of Dicarboxylic Esters
Dyker, Gerald
supporting information, p. 6773 - 6776 (2021/12/31)
A new method for the monohydrolysis of dicarboxylic esters is presented, involving as key step a silanolysis at elevated temperatures at the silica gel surface. In the second step, the surface bound silyl esters are cleaved off under mild conditions, giving a straightforward and fast access to half esters. Based on recovered starting material generally yields well above 70 % are achieved, both, with stiff aromatic as well as flexible aliphatic substrates, as long as the ester groups involved are remote enough from each other. Otherwise competing reactions are becoming determinative, anhydride formation in the case of phthalates and decarbonylative fragmentation in the case of malonates. The new method was also successfully tested on a multigram scale with a minimalistic apparatus setup.
Benzene tricarboxamide derivatives with lipid and ethylene glycol chains self-assemble into distinct nanostructures driven by molecular packing
Aljuaid, Nada,Hamley, Ian W.,Ruokolainen, Janne,Seitsonen, Jani,Tully, Mark
supporting information, p. 8360 - 8363 (2021/08/25)
The self-assembly in aqueous solution of benzene-1,3,5-tricarboxamide (BTA) bearing one alkyl chain and two PEG (polyethylene glycol) chains or two alkyl chains and one PEG chain yields completely distinct nanostructures. Two series of derivatives were sy
Efficient cycling utilization of solar-thermal energy for thermochromic displays with controllable heat output
Yang, Weixiang,Feng, Yiyu,Si, Qianyu,Yan, Qinghai,Long, Peng,Dong, Liqi,Fu, Linxia,Feng, Wei
supporting information, p. 97 - 106 (2019/01/03)
Use of solar energy as a source of heat is an important method of storing and providing clean energy for thermal management. However, the difficulties associated with combining the high-energy storage and high-rate heat release of solar thermal storage (S
Optimized reaction pair of the Cyshis tag and Ni(II)-Nta probe for highly selective chemical labeling of membrane proteins
Zenmyo, Naoki,Tokumaru, Hiroki,Uchinomiya, Shohei,Fuchida, Hirokazu,Tabata, Shigekazu,Hamachi, Itaru,Shigemoto, Ryuichi,Ojida, Akio
supporting information, p. 995 - 1000 (2019/07/18)
Chemical labeling of proteins with synthetic molecular probes offers the possibility to probe the functions of proteins of interest in living cells. However, the methods for covalently labeling targeted proteins using complementary peptide tag-probe pairs are still limited, irrespective of the versatility of such pairs in biological research. Herein, we report the new CysHis tag-Ni(II) probe pair for the specific covalent labeling of proteins. A broad-range evaluation of the reactivity profiles of the probe and the CysHis peptide tag afforded a tag-probe pair with an optimized and high labeling selectivity and reactivity. In particular, the labeling specificity of this pair was notably improved compared to the previously reported one. This pair was successfully utilized for the fluorescence imaging of membrane proteins on the surfaces of living cells, demonstrating its potential utility in biological research.
Tri-Orthogonal Scaffolds for the Solid-Phase Synthesis of Peptides
Pícha, Jan,Fabre, Benjamin,Budě?ínsky, Milo?,Hajduch, Jan,Abdellaoui, Mehdi,Jirá?ek, Ji?í
, p. 5180 - 5192 (2018/08/01)
Multi-orthogonal scaffolds can be useful for the attachment of several different compounds to the same central skeleton. Such compounds can find applications in the development of protein mimics because of their potential to mimic several distant epitopes
Tubular and lamellar hydrogen-bonding molecular assemblies of isophthalic acid derivatives bearing a -CONHCnH2 n +1 chain
Lv, Chao,Takeda, Takashi,Hoshino, Norihisa,Akutagawa, Tomoyuki
, p. 22250 - 22258 (2018/06/26)
Isophthalic acid derivatives (CnIP), bearing alkylamide chains (-CONHCnH2n+1: n = 6, 10, 14, and 18) at the 5-position that can participate in hydrogen bonding, were prepared and evaluated for their hydrogen-bonding molecular assembl
A highly porous acylamide decorated MOF-505 analogue exhibiting high and selective CO2 gas uptake capability
Zheng, Baishu,Huang, Lu,Cao, Xiyang,Shen, Shaohua,Cao, Haifei,Hang, Cheng,Zeng, Wenjiang,Wang, Zhaoxu
, p. 1874 - 1881 (2018/04/03)
Porous metal-organic frameworks (MOFs) constructed from organic linkers and metal ions/clusters can provide special pore environments for selective CO2 capture. In this work, we designed and synthesized a highly porous acylamide-functionalized
Azo phenyl photo-thermal energy storing molecule as well as preparation method and application thereof
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Paragraph 0046-0048; 0061-0062; 0069-0070, (2018/09/11)
The invention provides an azo phenyl photo-thermal energy storing molecule which has the structure shown in the formula I. A single molecule contains two kinds of azobenzene molecules: two dicarboxylazobenzene units and one monoamino azobenzene unit, by u
Metal-induced supramolecular chirality inversion of small self-assembled molecules in solution
Kokan, Zoran,Peri?, Berislav,Vazdar, Mario,Marini?, ?eljko,Viki?-Topi?, Dra?en,Me?trovi?, Ernest,Kirin, Sre?ko I.
supporting information, p. 1945 - 1948 (2017/02/15)
A non-covalent self-assembled chiral alanyl aminopyridine ligand exhibits supramolecular chirality in solution, independent of the organic solvent used. The supramolecular chirality of the assemblies is completely inverted by complexation to zinc ions. To date, such a supramolecular metal-ligand system has not been reported in the literature.
Radiolabeled Dibenzodiazepinone-Type Antagonists Give Evidence of Dualsteric Binding at the M2 Muscarinic Acetylcholine Receptor
Pegoli, Andrea,She, Xueke,Wifling, David,Hübner, Harald,Bernhardt, Günther,Gmeiner, Peter,Keller, Max
supporting information, p. 3314 - 3334 (2017/05/05)
The dualsteric ligand approach, aiming at ligands with improved subtype selectivity, has been increasingly applied to muscarinic receptors (MRs). In this article, we present the synthesis and characterization of a M2R subtype-preferring radiola
