53116-59-9Relevant academic research and scientific papers
Catalytic transfer hydrogenolysis of 4-nitrobenzyl esters of cephalosporins
Albanese, Domenico,Leone, Mario,Penso, Michele,Seminati, Monica,Zenoni, Maurizio
, p. 2405 - 2408 (1998)
Cephalosporins 1a-d have been selectively hydrogenolysed to their corresponding acids 2a-d without isomerisation of the cephem double-bond using anhydrous ammonium formate or phosphinic acid as catalytic transfer agents in the presence of 10% pd/C.
C(3)-ALKOXYCEPHEMS
Spry, Douglas O.,Bhala, Anita R.
, p. 1653 - 1661 (2007/10/02)
The C(3)-hydroxycephems 1 undergo the Mitsunobu reaction to give a series of heretofore unavailable C(3)-alkoxycephems 2.
