53133-36-1Relevant academic research and scientific papers
Gold(i) complexes with heteroaryl phosphine ligands
Sarcher, Christian,Farsadpour, Saeid,Taghizadeh Ghoochany, Leila,Sun, Yu,Thiel, Werner R.,Roesky, Peter W.
, p. 2397 - 2405 (2014/02/14)
Gold(i) complexes ligated by phosphines with N-heterocycles in the periphery were prepared. First the synthesis of the ligands N- (diphenylphosphino)-4-(pyridin-2-yl)pyrimidin-2-amine (Hpypya) and N-(diphenylphosphino)-4-phenylpyrimidin-2-amine (Hphpya) a
Highly efficient synthesis of α,β-acetylenic aldehydes from terminal alkynes using DMF as the formylating reagent
Journet, Michel,Cai, Dongwei,DiMichele, Lisa M.,Larsen, Robert D.
, p. 6427 - 6428 (2007/10/03)
The formylation of lithium acetylides with DMF led to α,β-acetylenic aldehydes in excellent yields (>94%). A reverse quench into a phosphate buffer (10% aqueous KH2PO4,4 equiv) proved to be the key for this high- yielding reaction.
