4316-37-4

Basic information

• Product Name: Acetophenone diethyl ketal
• Synonyms: Acetophenone diethyl ketal;Benzene, (1,1-diethoxyethyl)-
• CAS NO: 4316-37-4
• Molecular Formula: C₁₂H₁₈O₂
• Molecular Weight: 194.27012
• Mol File: 4316-37-4.mol
• Article Data: 31

Chemical Properties

• Boiling Point: 231.7°Cat760mmHg
• Flash Point: 71.2°C
• Appearance: /
• Density: 0.962g/cm³
• Vapor Pressure: 0.0934mmHg at 25°C
• Refractive Index: 1.48
• CAS DataBase Reference: Acetophenone diethyl ketal(CAS DataBase Reference)
• NIST Chemistry Reference: Acetophenone diethyl ketal(4316-37-4)
• EPA Substance Registry System: Acetophenone diethyl ketal(4316-37-4)

Safety Data

• Hazardous Substances Data: 4316-37-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H18O2/c1-4-13-12(3,14-5-2)11-9-7-6-8-10-11/h6-10H,4-5H2,1-3H3

Upstream product

• 24154-16-3 α,α‐dibromoethybenzene 
• 141-52-6 sodium ethanolate 
• 7647-01-0 hydrogenchloride 
• 64-17-5 ethanol 
• 122-51-0 orthoformic acid triethyl ester 
• 98-86-2 acetophenone 
• 100-52-7 benzaldehyde 
• 78-39-7 Triethyl orthoacetate 
• 536-74-3 phenylacetylene 
• 2914-19-4 barium diethanolate 
• 6230-62-2 (1-ethoxyvinyl)benzene 
• 5684-32-2 2-methyl-2-phenyl-[1,3]oxathiolane 
• 16694-46-5 ethyl formimidate hydrochloride 

Downstream Products

• 6230-62-2 (1-ethoxyvinyl)benzene 
• 130597-97-6 (E)-4-(N,N-dimethylamino)-N-(1-phenylethylidene)aniline 
• 101448-09-3 1,1,3-triethoxy-3-phenylbutane 
• 109559-33-3 5-ethoxy-5-phenyl-hex-2-enal-diethylacetal 
• 102315-16-2 (+/-)-7-ethoxy-7-phenyl-octa-2ξ,4ξ-dienal-diethylacetal 
• 102550-84-5 9-ethoxy-9-phenyl-deca-2,4,6-trienal-diethylacetal 
• 91132-84-2 (1-phenyl-ethylidene)-carbamic acid ethyl ester 
• 109482-03-3 (Z)-3-Phenyl-2-trimethylsilanylmethyl-but-2-enoic acid ethyl ester 
• 73007-56-4 <18O>acetophenone 
• 98-86-2 acetophenone 
• 105-57-7 diethyl acetal 
• 4105-21-9 2-phenylimidazo[1,2-a]pyridine 
• 120810-61-9 (E)-N-(1-phenylethylidene)pyridin-2-amine 
• 7182-29-8 5-hydroxy-2-phenylbenzofuran 

Relevant articles and documents

Conjugate addition of acetal-derived benzyl radicals generated from low-valent titanium-mediated CO bond cleavage

A new method for the generation of benzyl radicals from acetals via low-valent titanium-mediated homolytic CO bond cleavage is presented. The low cost and availability of the developed titanium reagent enable efficient access to α-alkoxy carbon radical species via the developed reaction.

A fluorinated cobalt(III) porphyrin complex for hydroalkoxylation of alkynes

A fluorinated cobalt(III) porphyrin complex [Co(TPFPP)-NTf2·2C2H5OH, where TPFPP=5,10,15,20-tetrakis(penta-fluorophenyl)porphyrin, Tf=CF3SO2] promotes hydroalkoxylation of alkynes to give acetals in good to excellent yields. The acetals can be directly functionalized with nucleophiles in a one-pot procedure.

A facile procedure for acetalization of aldehydes and ketones catalyzed by cerium(III) trifluoromethanesulfonate

Aldehydes and ketones are readily protected in the presence of trialkyl orthoformate and a catalytic amount of cerium(III) trifluoromethanesulfonate under mild conditions to give the corresponding acetals in good to excellent yields. Due to the mild reaction conditions, this method is compatible with acid-sensitive substrates. Copyright