5316-80-3Relevant academic research and scientific papers
Synthesis and inhibition corrosion effect of two thiazole derivatives for carbon steel in 1 ?M HCl
Benali,Zebida,Maschke
, (2021/08/04)
Inhibition of C38 carbon steel corrosion by 4-methyl-3-phenyl-2(3H)-thiazolethione (TO1) and 4-methyl-2-(methylthio)-3- phenylthiazol-3-ium (ST1) in 1 ?M HCl was investigated by weight loss and electrochemical methods. All of the data obtained reveal that the two compounds act as good inhibitors in this media. At optimized concentration TO1 and ST1 showed the highest inhibition efficiency of 98.8% (2.10?4 ?M) and 93.86% (10?3 ?M) respectively. Polarization curves show that inhibitor molecules act as mixed type inhibitors. The impedance study showed that an increase in the concentration of the two inhibitors is accompanied by an increase in polarization resistance and a decrease in double layer capacitance. The Langmuir isotherm very well describes the adsorption of inhibitors to the surface of the corroding metal and the thermodynamic parameters showed that the adsorption of the two compounds was strong and chemical nature. X-ray photoelectron spectroscopy (XPS) confirms and describes the absorption of inhibitors under investigation on the metal surface.
4,5-Substituted ?C? cyclometalated thiazol-2-ylidene platinum(II) complexes-synthesis and photophysical properties
Leopold, Hendrik,Strassner, Thomas
, p. 7800 - 7812 (2017/07/13)
We report the synthesis of seven novel backbone functionalized N-phenyl-1,3-thiazol-2-ylidene platinum(ii) complexes and their photophysical properties. Electronically diverse N-phenyl-1,3-thiazol-2-thiones were prepared by a reaction of aniline with carb
Synthesis of new rhodacyanines analogous to MKT-077 under microwave irradiation
Kasmi-Mir, Souad,Djafri, Ayada,Hamelin, Jack,Paquin, Ludovic,Bazureau, Jean Pierre,Rahmouni, Mustapha
, p. 4017 - 4034 (2008/03/13)
We report here a synthesis of a new rhodacyanines 7X analogous to MKT-077 with quantitative yield using as starting material the thiazolinethione 1. Merocyanines 4 and their tosylates 5 have been prepared as intermediates for this class of compounds. The reactions leading to rhodacyanine 7X have been studied under microwave irradiation. Copyright Taylor & Francis Group, LLC.
Structural Aspects of Catalytic Activities of Thiazolium Salts in Benzoin Condensation Reaction in Methanol
Yano, Yumihiko,Tamura, Yoshiharu,Tagaki, Waichiro
, p. 740 - 744 (2007/10/02)
The rates of benzoin condensation catalyzed by thiazolium salts of varying structures have been determined in methanol containing triethylamine as the base by the method of gas chromatography.The condensation activity was observed not to be linearly corre
