53226-68-9Relevant academic research and scientific papers
Reactions of α-haloallyllithium derivatives with carbon, silicon, tin or boron halides and carbonyl compounds
Julia, Marc,Verpeaux, Jean-Noel,Zahneisen, Thomas
, p. 539 - 554 (2007/10/02)
A series of allylic halides have been converted into their α-carbanions with strong lithium bases, using different techniques.These have been compared in their reaction with various electrophiles leading to functionally substituted allyl derivatives.The influence of the counterion on the regio- and stereoselectivity has been investigated. allylic halides / α-halocarbanions / allylsilanes / allyltin derivatives / α-chlorohydrins / vinylepoxides / diastereoselectivity
Palladium-Catalyzed Selective Hydrogenolysis of Alkenyloxiranes with Formic Acid. Stereoselectivity and Synthetic Utility
Oshima, Masato,Yamazaki, Hiroyuki,Shimizu, Isao,Nisar, Mohammad,Tsuji, Jiro
, p. 6280 - 6287 (2007/10/02)
Selective hydrogenolysis of alkenyloxiranes to give homoallylic alcohols was carried out using formic acid in the presence of palladium-phosphine catalyst.The selectivity of the reaction depends on a nature and an amount of phosphine ligands.The reaction
