53380-82-8

Basic information

• Product Name: Silanamine, N,N'-[methylenebis(diphenylphosphoranylidyne)]bis[1,1,1-trimethyl-
• CAS NO: 53380-82-8
• Molecular Formula: C31H40N2P2Si2
• Molecular Weight: 558.791
• Mol File: 53380-82-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silanamine, N,N'-[methylenebis(diphenylphosphoranylidyne)]bis[1,1,1-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, N,N'-[methylenebis(diphenylphosphoranylidyne)]bis[1,1,1-trimethyl-(53380-82-8)
• EPA Substance Registry System: Silanamine, N,N'-[methylenebis(diphenylphosphoranylidyne)]bis[1,1,1-trimethyl-(53380-82-8)

Safety Data

• Hazardous Substances Data: 53380-82-8(Hazardous Substances Data)

Upstream product

• 4648-54-8 trimethylsilylazide 
• 2071-20-7 bis-diphenylphosphinomethane 

Downstream Products

• 26040-41-5 methylenebis(diphenyldifluorophosphorane) 
• 58495-94-6 3,3,5,5-tetraphenyl-4H-1,2,6,3λ⁵,5λ⁵-thiadiazadiphosphorin-1,1-dioxide 
• 18306-29-1 bis(trimethylsilyl)sulphate 
• 113633-68-4 ((CH₃)3SiO)2OsO₂(NP(C₆H₅)2CH₂P(C₆H₅)2N) 
• 106865-59-2 CH₂(P(C₆H₅)2N)2WCl₄ 
• 245679-04-3 Zn(CH₃)(HC((C₆H₅)2PNSi(CH₃)3)2) 
• 473773-88-5 Sm(C(Ph2P=NSiMe3)2-κ3C,N,N')(NCy2)(THF) 
• 365275-72-5 [Cp*TiCl₂((NPPh₂)CH₂(Ph₂PNSiMe₃)-kN)] 
• 556112-67-5 NiCl₂(bis[trimethylsilyliminodi(phenyl)phosphoranyl]methane)*CH₂Cl₂ 
• 1027330-35-3 [Y(bis(N-(SiMe₃)diphenyliminophosphorano)methanediido)(CH₂SiMe₃)(THF)] 
• 1140969-52-3 Y(OC₄H₈)2I(C(P(C₆H₅)2NSi(CH₃)3)2) 

Relevant articles and documents

Structure of the telluroketone TeC(PPh2NSiMe3) 2 coordinated to an Li8O6 cluster

The reaction of Li2[C(PPh2NSiMe3) 2] with elemental tellurium in THF was carried out in an attempt to generate the tellurocarbonyl dianion [TeC(PPh2NSiMe3) 2]2- as the dilithium derivative. This thermally unstable tridentate ligand was characterized by 31P and 7Li NMR spectroscopy. Attempted recrystallization gave yellow crystals, which were shown by X-ray crystallography to be a neutral, centrosymmetric complex comprised of two molecules of the novel telluroketone [TeC(PPh2NSiMe 3)2] stabilized by N,Te,N coordination to LiOLi units of the rhombic dodecahedral cluster [Li8(μ5-O) 2(μ5-OH)4(C4H8O) 4].