5340-59-0Relevant academic research and scientific papers
A direct and sustainable synthesis of tertiary butyl esters enabled by flow microreactors
Degennaro, Leonardo,Maggiulli, Daniela,Carlucci, Claudia,Fanelli, Flavio,Romanazzi, Giuseppe,Luisi, Renzo
supporting information, p. 9554 - 9557 (2016/08/01)
Tertiary butyl esters find large applications in synthetic organic chemistry. A straightforward method for the direct introduction of the tert-butoxycarbonyl group into a variety of organic compounds has been developed using flow microreactor systems. The resultant flow process was more efficient, versatile and sustainable compared to the batch.
Synthesis of symmetrical ketones from Grignard reagents and 1,1′-carbonyldiimidazole
Bottalico, Daniela,Fiandanese, Vito,Marchese, Giuseppe,Punzi, Angela
experimental part, p. 2316 - 2318 (2010/02/28)
Coupling reactions of 1,1′-carbonyldiimidazole with Grignard reagents provide a rapid and straightforward method for the synthesis of symmetrical ketones. Georg Thieme Verlag Stuttgart.
The First Phase-transfer catalysed Reactions of Trialkylboranes. A Highly Facile Synthesis of Trialkylmethanols from Alkenes
Junchai, Bai,Hongxun, Ding
, p. 323 (2007/10/02)
The phase-transfer catalysed reactions of trialkylboranes, generated in situ via hydroboration of alkenes, with chloroform and aqueous sodium hydroxide, followed by treatment with hydrogen peroxide, provide an economic and convenient metod for the synthesis of trialkylmethanols.
LITHIUM TRIS(PHENYLTHIO)METHANE FOR THE HOMOLOGATION OF TRIALKYLBORANES: CONVENIENT SYNTHESES OF KETONES AND t-CARBINOLS
Pelter, Andrew,Rao, J. Madhusudhana
, p. 65 - 70 (2007/10/02)
Lithium tris(phenylthio)methane is a readily available, cheap reagent for the production of ketones and t-carbinols from trialkylboranes.The scope and limitations of the reactions are indicated as are some of its unique features.
Synthesis of Ketones and Tertiary Alcohols from Trialkylboranes. Use of Lithium Tris(phenylthio)methanide
Pelter, Andrew,Rao, J. Madhusudhana
, p. 1149 - 1150 (2007/10/02)
The interaction of lithium tris(phenylthio)methanide with trialkylboranes followed by oxidation allows the production of ketones or tertiary alcohols in good yields under mild conditions.
