5348-83-4

Usage

InChI:InChI=1/C28H58S2/c1-3-5-7-9-11-13-15-17-19-21-23-25-27-29-30-28-26-24-22-20-18-16-14-12-10-8-6-4-2/h3-28H2,1-2H3

Upstream product

• 112-71-0 1-Bromotetradecane 
• 2079-95-0 1-tetradecanethiol 
• 7553-56-2 iodine 
• 64-19-7 acetic acid 

Downstream Products

• 2079-95-0 1-tetradecanethiol 

Relevant academic research and scientific papers

Preparation, structures, and physical properties of tetrakis(alkylthio) tetraselenafulvalene (TTCn-TSeF, n = 1-15)

A series of tetrakis(alkylthio)tetraselenafulvalene compounds (TTC n-TSeF, n = 1-15) were prepared by a one-step reaction between dialkyl disulfide and tetralithiated TSeF. Molecular properties (redox potentials and optical absorptions in solution) and solid-state properties (thermal behaviors, electric conductivities, and molecular and crystal structures for n = 1 and 10) were studied. TTCn-TSeF compounds are weak electron donor molecules and characterized by small on-site Coulomb repulsion. TTC1-TSeF has a high-dimensional conduction network owing to the presence of highdimensional heteroatomic contacts, "Atomic-Wire Effect." The π-moieties of TTC10-TSeF were fastened by the alkyl chains ("Fastener Effect") to form π-columns and there are a variety of short heteroatomic contacts resulting in two dimensional electronic structure. Electrical conductivity exhibited peculiar enhancement for n = 1 and 7 ≤ n ≤ 14 owing to the presence of high-dimensional conduction paths. These compounds may manifest high carrier mobility, and are good candidates for the field-effect transistor channel based on the advantageous features: low dark conductivity, low donor ability, on-site Coulomb repulsion energy, high-dimensional π-electron structure, and high solubility in organic solvents.

Cobalt phthalocyanine mediated aerobic oxidation of thiols: A simple and convenient preparation of disulphides

Cobalt phthalocyaninetetrasulphonamide/tetrasodium salt of cobalt tetrasulphophthalocyanine catalyzed oxidation with molecular oxygen form a simple, efficient and environmentally acceptable synthetic tool for the oxidation of thiols to disulphides in excellent yields, under mild conditions and without any side reactions.

Hydrotalcite clay-catalysed air oxidation of thiols

Hydrotalcite is an efficient catalyst for air oxidation of a variety of aromatic, aliphatic and alicyclic thiols in hexane, affording the corresponding disulfides in excellent to quantitative yields under mild and neutral conditions.

Simple Oxidation of Thiols with Sodium lodate under Solid-Solution Biphasic Conditions

A variety of aromatic, aliphatic, and alicyclic thiols were readily oxidised with a combination of sodium iodate and Chromatographic neutral alumina in hexane to afford the corresponding disulfides in excellent yields under mild and neutral conditions.

Alumina: An Efficient and Reusable Catalyst for the Oxidative Coupling of Thiols with DMSO

An inexpensive combination of common laboratory reagents, dimethyl sulfoxide (DMSO) and Chromatographic neutral alumina, gives an efficient, selective, and high-yielding oxidation of aromatic, aliphatic and alicyclic thiols to the corresponding disulfides in excellent yields under relatively mild conditions.

Oxidation by Chemical Manganese Dioxide. Part 2.1 Simple and High-yielding Synthesis of Symmetrical Disulfides via the Oxidative Coupling of Thiols

Aromatic, aliphatic, and alicyclic thiols readily underwent oxidative coupling with chemical manganese dioxide in hexane to afford the corresponding disulfides in essentially quantitative yields under relatively mild conditions.

An environmentally friendly oxidation of thiols to disulfides by calcium hypochlorite and montmorillonite K10 in hexane

Aromatic, aliphatic, and alicyclic thiols can be readily oxidized to the disulfides quantitatively by calcium hypochlorite and moist Montmorillonite K10 under mild and neutral conditions.