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5349-60-0

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5349-60-0 Usage

Uses

rac-1-(4’-Methoxyphenyl)propanol (cas# 5349-60-0) is a compound useful in organic synthesis.

Check Digit Verification of cas no

The CAS Registry Mumber 5349-60-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,3,4 and 9 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 5349-60:
(6*5)+(5*3)+(4*4)+(3*9)+(2*6)+(1*0)=100
100 % 10 = 0
So 5349-60-0 is a valid CAS Registry Number.

5349-60-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-(4-methoxyphenyl)propan-1-ol

1.2 Other means of identification

Product number -
Other names 1-(4-methoxy-phenyl)-propanol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5349-60-0 SDS

5349-60-0Relevant articles and documents

2,2′-Bipyridine-α,α′-trifluoromethyl-diol ligand: Synthesis and application in the asymmetric Et2Zn alkylation of aldehydes

Lauzon, Samuel,Ollevier, Thierry

supporting information, p. 11025 - 11028 (2021/11/03)

A chiral 2,2′-bipyridine ligand (1) bearing α,α′-trifluoromethyl-alcohols at 6,6′-positions was designed in five steps affording either the R,R or S,S enantiomer with excellent stereoselectivities, i.e. 97% de, >99% ee and >99.5% de, >99.5% ee, respectively. The key step for reaching high levels of stereoselectivity was demonstrated to be the resolution of the α-CF3-alcohol using (S)-ibuprofen as the resolving agent. An initial application for the 2,2′-bipyridine-α,α′-CF3-diol ligand was highlighted in the ZnII-catalyzed asymmetric ethylation reaction of aromatic, heteroaromatic, and aliphatic aldehydes. Synergistic electron deficiency and steric hindrance properties of the newly developed ligand afforded the corresponding alcohols in good to excellent yields (up to 99%) and enantioselectivities (up to 95% ee). As observed from single crystal diffraction analysis, the complexation of the 2,2′-bipyridine-α,α′-CF3-diol ligand generates an unusual hexacoordinated ZnII.

Production of enantiopure chiral aryl heteroaryl carbinols using whole‐cell Lactobacillus paracasei biotransformation

?ahin, Engin

, p. 549 - 557 (2020/01/08)

Aryl and heteroaryl chiral carbinols are useful precursors in the synthesis of drugs. Lactobacillus paracasei BD87E6, which is obtained from a cereal based fermented beverage, was investigated as whole cell biocatalyst for the bioreduction of different ketones (including aromatic, hetero-aromatic and fused bicyclic ketone) into chiral carbinols, which can be used as a pharmaceutical intermediate. The study shows that bioreduction of aryl, heteroaryl and fused bicyclic ketone (1–5) to their corresponding chiral carbinols (1a–5a) in excellent enantioselectivity (>99%) with high yields. This study gave the first example for an enantiopure production of (S)-6-chlorochroman-4-ol (3a), which has many antioxidant activity, by a biological method. For asymmetric bioreduction of other prochiral ketones, these results open way to use of L. paracasei BD87E6 as biocatalysts. Also, the present process shows a hopeful and alternative green synthesis for the production of enantiopure carbinols in a mild, inexpensive and environmentally friendly process.

Compound, resin, and a method for manufacturing a resist pattern a resist composition (by machine translation)

-

Paragraph 0209, (2020/01/28)

[A] producing a resist pattern having a good CD uniformity compound, resin and resist composition. (I) a compound represented by the formula [a], and a resin composition. [In the formula (I), R1 Is, a hydrogen atom or a methyl group. R2 The, 1 - 6 carbon atoms in the alkyl group. R3 Is, a hydrogen atom or an alkyl group of 1 - 6 represent. The Ar, substituted divalent aromatic hydrocarbon group having a carbon number of 6 - 36 may represent 2. R4 The, 1 - 12 carbon atoms have a substituent which may be fluorinated alkyl groups. ][Drawing] no (by machine translation)

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