5362-74-3Relevant articles and documents
Reversible Carbon-Nitrogen Bond Formation in the Isomerisation of Triosmium Compounds derived from t-Butyldiazomethane (ButCHN2); the X-Ray Crystal Structure of tCH=NNCO)(CO)8(PMe2Ph)>
Deeming, Antony J.,Fuchita, Yoshio,Hardcastle, Kenneth,Henrick, Kim,McPartlin, Mary
, p. 2259 - 2264 (1986)
The dihydride reacts with the diazoalkane ButCHN2 to give tCH=NNH)-(CO)10> in the same way as reported for other diazoalkanes.A compound believed to be t)(μButCH=NNH)(CO)10> is
Diborylalkyllithium Salts Trigger Regioselective Ring Opening of Vinyl Aziridines
Salvado, Oriol,Gava, Riccardo,Fernández, Elena
supporting information, p. 9247 - 9250 (2019/11/14)
gem-Diborylalkanes treated with LiTMP produce α-diborylalkane lithium bases that perform nucleophilic attack on vinyl aziridines with controlled regioselectivity. Preferred SN2 diborylalkylation ring opening reaction on the less sterically hind
Formal carbon insertion of n-tosylhydrazone into B-B and B-Si bonds: Gem-diborylation and gem-silylborylation of sp3 carbon
Li, Huan,Shangguan, Xianghang,Zhang, Zhikun,Huang, Shan,Zhang, Yan,Wang, Jianbo
supporting information, p. 448 - 451 (2014/04/03)
A convenient method is developed to synthesize 1,1-diboronates from the corresponding N-tosylhydrazones. This method is also applicable to synthesize 1-silyl-1-boron compounds. Meanwhile, derivatization and consecutive Pd-catalyzed cross-coupling reaction
