Reversible Carbon-Nitrogen Bond Formation in the Isomerisation of Triosmium Compounds derived from t-Butyldiazomethane (ButCHN2); the X-Ray Crystal Structure of tCH=NNCO)(CO)8(PMe2Ph)>

DOI: 10.1039/DT9860002259

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2259 - 2264 (1986)

Update date:2022-08-12

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Authors:

Deeming, Antony J.

Fuchita, Yoshio

Hardcastle, Kenneth

Henrick, Kim

McPartlin, Mary

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Article abstract of DOI:10.1039/DT9860002259

The dihydride reacts with the diazoalkane Bu^tCHN2 to give tCH=NNH)-(CO)10> in the same way as reported for other diazoalkanes.A compound believed to be t)(μBu^tCH=NNH)(CO)10> is

Full text of DOI:10.1039/DT9860002259

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