53645-21-9

Usage

Uses

Used in Pharmaceutical Industry:
(Z)-1-Bromon-2-ene is used as a reagent for the synthesis of pharmaceuticals, contributing to the development of new medications and therapies.
Used in Agrochemical Industry:
(Z)-1-broMonon-2-ene is also utilized as a reagent in the production of agrochemicals, which are essential for enhancing crop protection and agricultural productivity.
Used in Industrial Chemicals Production:
(Z)-1-Bromon-2-ene is employed in the synthesis of other industrial chemicals, playing a crucial role in the manufacturing process of various products.
Used in Material Development:
(Z)-1-broMonon-2-ene has potential applications in the development of new materials, which can be beneficial for creating innovative and improved products in different industries.
Used in Academic Research:
(Z)-1-Bromon-2-ene is also used as a reagent in academic research, where it contributes to the advancement of scientific knowledge and the discovery of new chemical reactions and processes.

InChI:InChI=1/C8H15Br/c1-2-3-4-5-6-7-8-9/h6-7H,2-5,8H2,1H3/b7-6-

Upstream product

• 20739-58-6 2-octyn-1-ol 
• 26001-58-1 (Z)-oct-2-en-1-ol 
• 113120-16-4 Toluene-4-sulfonic acid (Z)-oct-2-enyl ester 
• 110-53-2 1-Bromopentane 
• 16491-64-8 2-octin-1-yl acetate 
• 122712-60-1 (Z)-2-(oct-2-en-1-yloxy)tetrahydro-2H-pyran 
• 628-71-7 1-Heptyne 
• 628-17-1 amyl iodide 
• 36602-98-9 2-(oct-2-yn-1-yloxy)tetrahydro-2H-pyran 
• 107691-96-3 (Z)-1-benzyloxy-2-octene 

Downstream Products

• 21944-96-7 (Z)-undec-5-en-2-one 
• 81677-38-5 tert-Butyl-diphenyl-[((2E,7Z)-trideca-2,7-dien-4-ynyl)oxy]-silane 
• 85250-56-2 (trans-Oct-2-enyl) phenyl sulfide 
• 91789-07-0 (cis-Oct-2-enyl) phenyl sulfide 
• 1394257-22-7 (S,2E,6Z)-4-(benzyloxy)dodeca-2,6-dienal 
• 1394257-23-8 (S,Z)-2-(benzyloxy)dec-4-enal 
• 1394257-30-7 (S,Z)-methyl 2-(benzyloxy)dec-4-enoate 
• 1394257-32-9 (+/-)-(Z)-methyl 2-(benzyloxy)dec-4-enoate 
• 1394257-24-9 (S,Z)-2-(benzyloxy)-1-(1-methyl-1H-imidazol-2-yl)dec-4-en-1-one 
• 1394257-31-8 (+/-)-(Z)-2-(benzyloxy)-1-(1-methyl-1H-imidazol-2-yl)dec-4-en-1-one 
• 57074-37-0 (Z)-4-decen-1-ol 
• 54844-65-4 (Z)-6-heneicosen-11-one 
• 7367-84-2 (Z)-4-decenoic acid ethyl ester 
• 78037-99-7 (5S)-(6E,8Z,11Z,14Z)-5-hydroxy-eicosa-6,8,11,14-tetraenoic acid, methyl ester 

Relevant academic research and scientific papers

BOTPPI, a new Wittig salt for the synthesis of 12-(S)-hydroxy- eicosatetraenoic acid [12-(S)-HETE]

An efficient route to (Z)-(8-benzyloxy-8-oxooct-3-en-1-yl) triphenylphosphonium iodide, or BOTPPI, is disclosed, complete with full experimental details, NMR spectra, and HRMS data. BOTPPI serves as a surrogate for (Z)-(8-methoxy-8-oxooct-3-en-1-yl)triphe

5-F2t-isoprostane, a human hormone?

Syntheses of the four enantiomerically pure diastereomers of 5-F2t-isoprostane (5-8) are described. The key step is the lipase-catalyzed chemo-enzymatic resolution of the racemic diol 40 to give the mono-acetates 41 and 42. The enantiomerically

EXO- AND ENDOHORMONES, XVI SYNTHESIS OF (4E, 7Z)-4,7-TRIDECADIEN 1-YL ACETATE, THE SEX PHEROMONE FOR THE LEAFMINER LITHOCOLLETIS CORYLIFOLIELLA

The synthesis of the sex pheromone of the leafminer moth, Lithocolletis corylifoliella, (4E, 7Z)-4,7-tridecadien-1-yl acetate, was based on a C5+C8 scheme.The coupling reaction took place between the Grignard reagent of 4-pentin-1-1-oic acid and 1-bromo-2Z-octene.Propargylic alcohol was used as a starting material in order to obtain the two synthons.

DIRECT CONVERSION OF TETRAHYDROPYRANYLATED ALCOHOLS TO THE CORRESPONDING BROMIDES

Various tetrahydro-2 pyranyl protected alcohols are converted into the corresponding bromides by PPh3/CBr4, with inversion of configuration, and high in yield.

PREPARATIVE SYNTHESIS OF TOSYLATES OF UNSATURATED ALCOHOLS AND UNSATURATED BROMIDES UNDER PHASE TRANSFER CONDITIONS

A preparative synthetic method has been developed for tosylates of unsaturated alcohols and their conversion to bromides under phase transfer conditions in the case of alkyn-1-ols, E- and Z-alken-1-ols, 3-methyl-3-buten-1-ol and cyclopropylmethanol.

The Preparation of Some Octenyl Sulfides from Oct-1-en-3-ol and Oct-2-en-1-ol

(E)- and (Z)-1-(Phenylthio)oct-2-ene, (E)-1-(methylthio)- and 1-(t-butylthio)-oct-2-ene, S- N,N-dimethylthiocarbamate, S- N,N-dimethylthiocarbamate, (E)-(oct-2-enylthio)benzothiazole, and S- N,N,N',N'-tetramethylphosphorodiamidothioate have been prepared by nucleophilic substitution reactions and - and -sigmatropic shifts involving intermediates prepared from oct-1-en-3-ol and (E)- and (Z)-oct-2-en-1-ol.

ALLYLATION OF GRIGNARD REAGENTS: ITS APPLICATION FOR THE SYNTHESIS OF (4E,7Z)-4,7-TRIDECADIENYL ACETATE, A SEX PHEROMONE OF POTATO TUBERWORM MOTH

Alkylmagnesium halides have been found to react with (Z)-4-benzyloxy-1-chloro-2-butene in presence of HMPA to produce a rearranged product 3-alkyl-4-benzyloxy-1-butene, while the absence of HMPA a normal product (Z)-1-alkyl-4-benzyloxy-2-butene resulted as the predominant product.Latter product has been utilized for the synthesis of (4E,7Z)-4,7-tridecadienyl acetate, a sex pheromone of potato tuberworm moth.

Total Synthesis of (+/-)-12-Hydroxy-5(Z),8(Z),10(E),14(Z)-eicosatetraenoic Acid (12-HETE)

A total synthesis of 12-HETE is reported which incorporates an oxidative cleavage of an appropriately substituted furan to provide a functionalized trans-allylhydroxy fragment which is subsequently elaborated in an operationally simple manner affording a practical preparation of 12-HETE.

Synthesis of Heptadeca-1,8Z,11Z-triene

The bromide (III), obtained from oct-2Z-en-1-ol (II) by treatment with PBr3/pyridine, reacts smoothly with 3-(tetrahydro-2-pyranyloxy)propynylmagnesium bromide to give IV which loses the protective pyranyl moiety when reacted with PTS/methanol to yield the alcohol (V).Catalytic hydrogenation of V in the presence of Lindlar's catalyst affords the dienol (VI) which is converted into the corresponding mesylate (VII) on reaction with MsCl/TEA.Coupling of VII with hex-1-enylmagnesium bromide in THF/HMPA at 0 deg C provides the title compound (I).

A Convenient Synthesis of (Z)-5-Undecen-2-one, Sex Pheromone from the Pedal Gland of Bontebok

Oct-2-yn-1-ol (II) on catalytic hydrogenation over 5percent Lindlar's catalyst yields (Z)-2-octen-1-ol (III) which is transformed into 1-bromo-2(Z)-octene (IV) by treatment with PBr3.Alkylation of α-lithioacetone dimethylhydrazone with IV in THF at -78 deg C followed by hydrolysis of the resulting hydrazone with NaIO4 at pH 7 results in formation of the title compound (I).