53907-33-8

Basic information

• Product Name: acetic acid 1-bromo-2-oxo-2-phenyl-ethyl ester
• Synonyms: acetic acid 1-bromo-2-oxo-2-phenyl-ethyl ester
• CAS NO: 53907-33-8
• Molecular Weight: 257.084
• Mol File: 53907-33-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: acetic acid 1-bromo-2-oxo-2-phenyl-ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: acetic acid 1-bromo-2-oxo-2-phenyl-ethyl ester(53907-33-8)
• EPA Substance Registry System: acetic acid 1-bromo-2-oxo-2-phenyl-ethyl ester(53907-33-8)

Safety Data

• Hazardous Substances Data: 53907-33-8(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 506-96-7 Acetyl bromide 
• 78146-52-8 phenylglyoxal monohydrate 

Downstream Products

• 93-58-3 benzoic acid methyl ester 
• 532-32-1 sodium benzoate 
• 506-96-7 Acetyl bromide 
• 1074-12-0 phenylglyoxal hydrate 
• 78146-52-8 phenylglyoxal monohydrate 

Relevant articles and documents

Polymer-Supported Bisacetoxybromate(I) Anion - An Efficient Co-Oxidant in the TEMPO-Mediated Oxidation of Primary and Secondary Alcohols

A polymer-bound reagent for the efficient oxidation of primary alcohols to aldehydes and secondary alcohols to ketones in the presence of a catalytic amount of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO) is described. The oxidation process is particular mild and allows one to prepare aldehydes with α-chirality without racemization. This also includes the synthesis of α-aminoaldehydes. In most cases, work-up of this heavy metal-free oxidation is achieved by simple filtration followed by removal of the solvent. Insight into the role of the bromate(I) anion in the oxidation process was gained from the TEMPO-mediated oxidation of benzaldehyde in the presence of the hypochlorite anion loaded on an anion exchange resin.

Ester derivatives and process for production thereof

There are provided novel ester derivatives represented by the following formula(I): STR1 wherein, R1 represents methyl, ethyl, isopropyl, t-butyl, or phenyl; R2 represents phenyl, methoxy, ethoxy, isopropanoxy, or t-butanoxy; and X r