54036-90-7

Upstream product

• 1070-89-9 sodium hexamethyldisilazane 
• 4039-32-1 lithium hexamethyldisilazane 
• 50732-21-3 N,N,N'-tris(trimethylsilyl)phosphenimidous amide 
• 10294-34-5 boron trichloride 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 68437-87-6 ((CH₃)3Si)2NP(C₆H₅)(CH₃) 
• 120-12-7 anthracene 
• 1394283-61-4 [(HMDS)P]3 
• 1394283-60-3 7-hexamethyldisilazane-2,3:5,6-dibenzo-7-phosphabicyclo[2,2,1]hepta-2,5-diene 
• 476622-94-3 P-n-propyl-P-phenoxy-N,N-bis(trimethylsilyl)aminophosphine 
• 102817-39-0 P-(2,4,6-tri-tert-butylphenyl)-P'-diphosphene 

Relevant academic research and scientific papers

Development of a one-pot in situ synthesis of poly(dichlorophosphazene) from PCl3

A method for the one-pot synthesis of poly(dichlorophosphazene) from PCl3 was developed. The method was a combination of synthesis of Cl3P=NSiMe3 monomer and living cationic polymerization method. The one-pot synthesis method provided an alternative way for the preparation of [N=PCl2]n. The results show that the yields of moisture stable derivative polymers [N=P(OCH2CF 3)2]n are in 40-50% range starting from PCl3.

Easy Access to Phosphine-Borane Building Blocks

In this paper, we highlight the synthesis of a variety of primary phosphine-boranes (RPH2?BH3) from the corresponding dichlorophosphines, simply by using Li[BH4] as reductant and provider of the BH3 protecting group. The method offers facile access not only to alkyl- and arylphosphine-boranes, but also to aminophosphine-boranes (R2NPH2?BH3) that are convenient building blocks but without the protecting BH3 moiety thermally labile and notoriously difficult to handle. The borane-protected primary phosphines can be doubly deprotonated using n-butyllithium to provide soluble phosphanediides Li2[RP?BH3] of which the phenyl-derivative Li2[PhP?BH3] was structurally characterized in the solid state.

Phenyl-methyl phosphazene derivatives for preparation and modification of hydrophobic properties of polymeric nonwoven textiles

This paper focuses on the preparation of two types of hydrophobic nanolayers using electrospinning technology. The first synthetic approach consists in direct fiberizing of polymeric phenyl-methyl-polyphosphazene Ph-Me(p) with the aim to preparing nanolay

Synthesis and Characterization of (Disilylanilino)Phosphines

(Graphical Abstract) The disilyl(4-bromo)aniline (Me3Si)2NC6H4Br (A) readily undergoes metal-halogen exchange to give the reactive organolithium derivative (Me3Si)2NC6H4/su

Synthesis of poly(alkyl/arylphosphazenes) via the ambient temperature phosphite-mediated chain-growth polycondensation of (N-Silyl) bromophosphoranimines

The room temperature addition of stoichiometric amounts of trimethyl phosphite, P(OMe)3, to N-silyl(halogeno)organophosphoranimines BrRR'PdNSiMe3 in chlorinated solvents led to the direct formation of high molecular weight polyphosph

Synthesis and characterization of mixed-substituent P-n-propyl-N-trimethylsilylphosphoranimines

One approach to the synthesis of polyphosphazenes is the condensation polymerization of phosphoranimines. In this work, several novel P-n-propyl-N-trimethylsilylphosphoranimines have been synthesized and characterized. Modifications to the literature synt

Secondary Aminodiphosphanes - Synthesis, Configuration and Properties

Both stereoisomers of 1-chloro-1,2-bisdiphosphane (4) are available by reaction of bis(trimethylsilyl)amino-dichlorophosphane with LiAlH4.Cl/H-exchange of (4) with LiAlH4 leads to the meso and racemic form of tetrakis(trimethylsilyl)diaminodiphosphane (5).Dynamic NMR data of the compounds 4 and 5 are discussed with respect to the molecular configurations and conformations.Equilibrium data for 5 indicate a gauche effect of about 3.8 kJ/mol. - Key words: Chloro-diaminodiphosphane, NMR Spectra, Configuration