5413-60-5

Basic information

• Product Name: TRICYCLODECENYL ACETATE
• Synonyms: TRICYCLODECENYL ACETATE;VERDYL ACETATE;3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-ylacetate;4,7-Methano-1H-inden-6-ol, 3a,4,5,6,7,7a-hexahydro-, acetate;4,7-Methano-1H-inden-6-ol,3a,4,5,6,7,7a-hexahydro-,acetate;4,7-Methanoinden-6-ol, 3a,4,5,6,7,7a-hexahydro-, acetate;7-methano-1h-inden-6-ol,3a,4,5,6,7,7a-hexahydro-acetate;7-methanoinden-6-ol,3a,4,5,6,7,7a-hexahydro-acetate
• CAS NO: 5413-60-5
• Molecular Formula: C₁₂H₁₆O₂
• Molecular Weight: 192.25
• EINECS: 226-501-6
• Mol File: 5413-60-5.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 288.25°C (rough estimate)
• Flash Point: 101.8 °C
• Appearance: colorless to pale yellow clear liquid
• Density: 1.0240 (rough estimate)
• Vapor Pressure: 0.0137mmHg at 25°C
• Refractive Index: 1.5100 (estimate)
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility: 571.429g/L in organic solvents at 20 ℃
• PKA: 0[at 20 ℃]
• Water Solubility: 10μg/L at 30℃
• CAS DataBase Reference: TRICYCLODECENYL ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: TRICYCLODECENYL ACETATE(5413-60-5)
• EPA Substance Registry System: TRICYCLODECENYL ACETATE(5413-60-5)

Safety Data

• Hazardous Substances Data: 5413-60-5(Hazardous Substances Data)

Usage

Occurrence

Has apparently not been reported to occur in nature.

Preparation

By hydration and acetylization of dicyclopentadiene.

Flammability and Explosibility

Flammable

InChI:InChI=1/C12H16O2/c1-7(13)14-12-6-8-5-11(12)10-4-2-3-9(8)10/h2-3,8-12H,4-6H2,1H3

Upstream product

• 13080-96-1 methylaceto acetate 
• 77-73-6 exo-tricyclo[5.2.1.0^2,6]deca-3,8-diene 
• 108-24-7 acetic anhydride 
• 108-05-4 vinyl acetate 
• 933-60-8 exo-dicyclopentadiene 
• 64-19-7 acetic acid 
• 1755-01-7 endo-Dicyclopentadien 
• 77-73-6 bi(cyclopentadiene) 

Relevant articles and documents

Stereoselective exo-addition to norbornenes of acetic acid generated from vinyl acetate in the presence of rhodium complexes

Rhodium complexes catalyzed decomposition of vinyl acetate with liberation of acetic acid and subsequent stereoselective exo-addition of the latter to norbornene and its derivatives under mild conditions.

Process for making tricyclodecenyl esters

A practical, economical process for making tricyclodecenyl esters is disclosed. After reacting a lower carboxylic acid and a dicyclopentadiene in the presence of triflic acid to form the ester, the reaction mixture is distilled in the presence of a base to isolate a fragrance-quality tricyclodecenyl ester. Adding enough base to neutralize the triflic acid enables a distillation-only purification, facilitates starting material recovery, and avoids drawbacks of a basic workup.

Production of "dicylate" perfume

The method for producing "dicylate" - tricyclo[5,2,1,02,6]dec-3-enyl-8(9)-acetate -from acetic acid and tricyclo[5,2,1,02,6]deca-3,8-diene has been improved. The reaction is carried out at a temperature of 130-170°C and spontaneous pressure, which enables the use of strong acids as catalysts to be discarded.