54134-93-9

Basic information

• Product Name: 3-CYCLOPROPYLANISOL
• Synonyms: 3-CYCLOPROPYLANISOL;Benzene, 1-cyclopropyl-3-Methoxy-;1-Cyclopropyl-3-methoxybenzene
• CAS NO: 54134-93-9
• Molecular Formula: C₁₀H₁₂O
• Molecular Weight: 148.2
• Mol File: 54134-93-9.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-CYCLOPROPYLANISOL(CAS DataBase Reference)
• NIST Chemistry Reference: 3-CYCLOPROPYLANISOL(54134-93-9)
• EPA Substance Registry System: 3-CYCLOPROPYLANISOL(54134-93-9)

Safety Data

• Hazardous Substances Data: 54134-93-9(Hazardous Substances Data)

Usage

General Description

3-Cyclopropylanisol, also known as 3-methoxy-cyclopropane, is a chemical compound with the molecular formula C8H12O. It is a colorless liquid with a sweet, floral odor and is commonly used as a fragrance ingredient in various cosmetic and personal care products. It is also used as a flavoring agent in food products. 3-Cyclopropylanisol is synthesized through the etherification of cyclopropanol with methanol in the presence of acid catalysts. It is considered to be relatively stable under normal conditions but should be handled with care due to its flammability and potential for causing eye and skin irritation.

Upstream product

• 626-20-0 3-methoxystyrene 
• 85622-93-1 temozolomide 
• 24743-14-4 1-allyl-3-methoxybenzene 
• 1607-29-0 bis((1-methylcyclopropyl)formyl)peroxide 
• 100-66-3 methoxybenzene 
• 25628-09-5 tetramethylammonium trifluoromethanesulphonate 
• 2398-37-0 3-methoxyphenyl bromide 
• 3002-94-6 cyclopropyllithium 
• 411235-57-9 cyclopropylboronic acid 

Relevant articles and documents

The copper-catalyzed ring-opening reactions of cyclopropanes by N-fluorobenzenesulfonimide toward N-allylsulfonamides

In this paper, we reported a copper-catalyzed ring-opening reaction of arylcyclopropanes by N-fluorobenzenesulfonimide, leading to N-allylsulfonamides in moderate to good yields. This procedure tolerated bromo, fluoro, trifluoromethyl, phenyl and alkyl groups in the phenyl, proceeding with a sequential ring-opening of arylcyclopropanes, and copper-mediated β-H elimination of alkyl radical.

Cyclopropanation of styrenes and stilbenes using lithiomethyl trimethylammonium triflate as methylene donor

Lithiomethyl trimethylammonium triflate, prepared from tetramethylammonium triflate, cyclopropanates several styrenes and stilbenes with electron-donating and selected electron-withdrawing substituents efficiently. Kinetic data support a stepwise nucleophilic addition-ring closure mechanism for this methylenation. This journal is the Partner Organisations 2014.

Facile synthesis of aryl(het)cyclopropane catalyzed by palladacycle

Sphos (2-dicyclohexylphosphino-2′,6′-dimethoxy-1,1′- biphenyl) adduct of cyclopalladated ferrocenylimine (IIe) exhibited highly catalytic activity for the Suzuki cross-coupling reaction of cyclopropylboronic acid with aryl(het) halides with 1 mol % catalyst loading. This process was applied to both of aryl and heteroaryl halides (Br and Cl), and made the various arylcyclopropane and heteroarylcyclopropane to be easily synthesized. A variety of substituents on the aryl halides, such as alkyl, acetyl, benzoyl, ether, formyl, carboxylate, methoxy, nitro and cyano were tolerated.