54197-71-6

Basic information

• Product Name: 3‐(2‐chlorophenyl)‐1‐phenylpropan‐1‐one
• Synonyms: 3‐(2‐chlorophenyl)‐1‐phenylpropan‐1‐one
• CAS NO: 54197-71-6
• Molecular Weight: 244.721
• Mol File: 54197-71-6.mol
• Article Data: 31

Chemical Properties

• CAS DataBase Reference: 3‐(2‐chlorophenyl)‐1‐phenylpropan‐1‐one(CAS DataBase Reference)
• NIST Chemistry Reference: 3‐(2‐chlorophenyl)‐1‐phenylpropan‐1‐one(54197-71-6)
• EPA Substance Registry System: 3‐(2‐chlorophenyl)‐1‐phenylpropan‐1‐one(54197-71-6)

Safety Data

• Hazardous Substances Data: 54197-71-6(Hazardous Substances Data)

Upstream product

• 22966-11-6 (2E)-3-(2-chlorophenyl)-1-phenylprop-2-en-1-one 
• 96-09-3 styrene oxide 
• 17849-38-6 2-Chlorobenzyl alcohol 
• 98-86-2 acetophenone 
• 2039-87-4 2-chlorostyrene 
• 611-73-4 Benzoylformic acid 
• 1794-45-2 (E)-3-(2-chlorophenyl)propenal 
• 98-80-6 phenylboronic acid 
• 65-85-0 benzoic acid 
• 98-85-1 1-Phenylethanol 
• 536-74-3 phenylacetylene 
• 89-98-5 2-chloro-benzaldehyde 
• 1643-28-3 3-(2-chlorophenyl)propanoic acid 
• 79-04-9 chloroacetyl chloride 

Downstream Products

• 54197-70-5 N-[3-(2-chlorophenyl)-1-phenyl-1-propylidene]-4-anisidine 

Relevant articles and documents

Photoredox-Catalyzed Hydroacylation of Olefins Employing Carboxylic Acids and Hydrosilanes

A hydroacylation reaction of alkenes has been achieved employing readily available carboxylic acids as the acyl source and hydrosilanes as a hydrogen source via photoredox catalysis. The combination of both single electron transfer and hydrogen atom transfer steps has dramatically expanded new applications of carboxylic acids in organic synthesis. The protocol also features extremely mild conditions, broad substrate scope, and good functional group tolerance, affording a novel and convenient approach to hydroacylation of alkenes.

C-C coupling formation using nitron complexes

A series of RuII (1), RhIII (2), IrIII (3, 4), IrI (5) and PdII (6-9) complexes of the 'instant carbene' nitron were prepared and characterized by 1H- and 13C-NMR, FT-IR and elemental analysis. The molecular structures of complexes 1-4 and 6 were determined by X-ray diffraction studies. The catalytic activity of the complexes (1-9) was evaluated in alpha(α)-alkylation reactions of ketones with alcohol via the borrowing hydrogen strategy under mild conditions. These complexes were able to perform this catalytic transformation in a short time with low catalyst and base amounts under an air atmosphere. Also, the PdII-nitron complexes (6-9) were applied in the Suzuki-Miyaura C-C coupling reaction and these complexes successfully initiated this reaction in a short time (30 minutes) using the H2O/2-propanol (1.5?:?0.5) solvent system. The DFT calculations revealed that the Pd0/II/0 pathway was more preferable for the mechanism

Electrochemical 1,4-reduction of α,β-unsaturated ketones with methanol and ammonium chloride as hydrogen sources

A sustainable, chemoselective 1,4-reduction of α,β-unsaturated ketones by means of an electrochemical method is presented, wherein the extremely inexpensive ammonium chloride (NH4Cl) is applied as the only additive. The reaction proceeds smoothly in the air at ambient temperature. Mechanistic studies reveal that both NH4Cl and solvent methanol work as hydrogen donors.