54255-65-1

Upstream product

• 108-95-2 phenol 
• 88-75-5 2-hydroxynitrobenzene 
• 6609-56-9 2-methoxy-benzonitrile 
• 579-75-9 2-Methoxybenzoic acid 
• 95-55-6 2-amino-phenol 
• 21615-34-9 2-Methoxybenzoyl chloride 

Downstream Products

• 13459-17-1 2-(2-methoxyphenyl)-1,3-benzoxazole 
• 1391741-54-0 methyl 4-((2-(2-methoxybenzamido)phenoxy)methyl)benzoate 
• 1391741-44-8 4-(2-(2-methoxybenzamido)phenoxy)phenyl acetate 
• 1391741-45-9 methyl 4-(2-(2-methoxybenzamido)phenoxy)benzoate 
• 1391741-47-1 N-(2-(4-nitrobenzyloxy)phenyl)-2-methoxybenzamide 
• 934669-09-7 2-methoxy-N-(2-(4-nitrophenoxy)phenyl)benzamide 
• 1391741-42-6 N-(2-(4-(dimethylamino)phenoxy)phenyl)-2-methoxybenzamide 
• 1391741-43-7 2-methoxy-N-(2-(4-methoxyphenoxy)phenyl)benzamide 

Relevant academic research and scientific papers

Conformations, equilibrium thermodynamics and rotational barriers of secondary thiobenzanilides

The article deals with conformational behaviour of 2-methoxy-2′-hydroxythiobenzanilides. The CS-NH group of these compounds preferentially adopts the Z-conformation. Entropy favours the Z-conformer over the E-conformer, whereas enthalpy slightly favours the E-conformer over the Z-conformer. The rotational barrier about the CS-NH bond was determined to be (81.5±0.4) kJ/mol. No significant rotational barrier was found on the Ar-CS and Ar-NH bonds. All experimental outcomes are compared with the results of quantum-chemical calculations.