544444-28-2

Basic information

• Product Name: (1R,4R)-4-Benzyloxymethyl-4-hydroxymethylcyclopent-2-en-1-ol
• Synonyms: (1R,4R)-4-Benzyloxymethyl-4-hydroxymethylcyclopent-2-en-1-ol
• CAS NO: 544444-28-2
• Molecular Weight: 234.295
• Mol File: 544444-28-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R,4R)-4-Benzyloxymethyl-4-hydroxymethylcyclopent-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4R)-4-Benzyloxymethyl-4-hydroxymethylcyclopent-2-en-1-ol(544444-28-2)
• EPA Substance Registry System: (1R,4R)-4-Benzyloxymethyl-4-hydroxymethylcyclopent-2-en-1-ol(544444-28-2)

Safety Data

• Hazardous Substances Data: 544444-28-2(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 261510-93-4 8-Phenyl-7,9-dioxaspiro[4.5]dec-2-ene 
• 175911-73-6 (1-(benzyloxymethyl)cyclopent-3-enyl)methanol 
• 76910-02-6 3-cyclopenten-1,1-dimethanol 
• 261510-99-0 (1α,3α,5α)-3-Benzyloxymethyl-6-oxabicyclo[3.1.0]hexane-3-methanol 

Downstream Products

• 544444-39-5 Acetic acid (1R,2R,3S,5R)-2-acetoxy-3-acetoxymethyl-3-benzyloxymethyl-5-(tert-butyl-diphenyl-silanyloxy)-cyclopentyl ester 
• 544444-33-9 (1R,4S,6R,7R)-benzoic acid 7-benzoyloxy-6-(tert-butyldiphenylsilanyloxy)-2-oxabicyclo[2.2.1]hept-4-ylmethyl ester 
• 544444-37-3 (1S,4S,6R,7R)-benzoic acid 4-benzoyloxymethyl-6-(6-aminopurin-9-yl)-2-oxabicyclo[2.2.1]hept-7-yl ester 
• 544444-40-8 Acetic acid (1R,2R,3S,5R)-2-acetoxy-3-acetoxymethyl-5-(tert-butyl-diphenyl-silanyloxy)-3-hydroxymethyl-cyclopentyl ester 
• 544444-29-3 (1R,2R,3R,5R)-3-benzyloxymethyl-3-hydroxymethyl-5-(tert-butyldiphenylsilanyloxy)cyclopentane-1,2-diol 
• 544444-36-2 (1R,4S,6S,7R)-benzoic acid 4-benzoyloxymethyl-6-trifluoromethanesulfonyloxy-2-oxabicyclo[2.2.1]hept-7-yl ester 
• 544444-34-0 (1S,4S,6R,7R)-benzoic acid 4-benzoyloxymethyl-6-hydroxy-2-oxabicyclo[2.2.1]hept-7-yl ester 
• 544444-35-1 (1S,4S,6S,7R)-benzoic acid 4-benzoyloxymethyl-6-hydroxy-2-oxabicyclo[2.2.1]hept-7-yl ester 
• 544444-41-9 C₂₁H₁₈O₆ 
• 544444-38-4 [(1R,4R)-1-Benzyloxymethyl-4-(tert-butyl-diphenyl-silanyloxy)-cyclopent-2-enyl]-methanol 

Relevant articles and documents

Mechanism and applications of lithium amide-induced asymmetric rearrangements of 4-substituted and 4,4-disubstituted cyclopentene oxides to cyclopentenols

The preparation and lithium amide-induced rearrangements of 1,2-dideuterated 4-substituted cyclopentene oxides 11 and 19 are described, providing insight into the deprotonation mechanisms operating in such systems. Highly enantioselective syntheses of 4-substituted cis-4-hydroxymethylcyclopent-2-en-1-ols 32a-c are described. Also described are asymmetric syntheses of prostaglandin precursor 40 and (+)-iridomyrmecin (48) via highly enantioselective rearrangement of the epoxide 3 and subsequent Ireland-Claisen rearrangement. The Royal Society of Chemistry 1999.