54445-57-7Relevant academic research and scientific papers
The Regio- and Stereoselectivities of the Reaction of Allyl Acetates and Silyl Ketene Acetals Catalyzed by Pd(0) Complexes: A New Route to Cyclopropane Derivatives
Carfagna, C.,Mariani, L.,Musco, A.,Sallese, G.,Santi, R.
, p. 3924 - 3927 (2007/10/02)
Pd(0) complexes of chelating phosphines catalyzed the coupling of allyl acetates and ketene silyl acetals to yield α-allylated carboxylic acid esters.Unexpectedly alkylation of the central carbon atom (C2) of the allyl groups was also observed with concomitant formation of cyclopropane derivatives.In both cases the silyl enolate attacked the allyl group from the side opposite Pd.The yield of the reaction was sensitive to the nature of the ligand coordinated with palladium.The 1,1'-bis(diphenylphosphino)ferrocene-Pd complex was the most effective catalyst.
Vinylogous Wolff Rearrangement. 4. General Reaction of β,γ-Unsaturated α'-Diazo Ketones
Smith, Amos B.,Toder, Bruce H.,Branca, Stephen J.
, p. 3995 - 4001 (2007/10/02)
The preparation and vinylogous Wolff rearrangement (VWR) of some 21 acyclic and monocyclic β,γ-unsaturated α'-diazo ketones are described.The resulting γ,δ-unsaturated esters are summarized in Tables I-VI.The rearrangement is promoted by CuSO4, Cu(AcAc)2,
