545442-25-9Relevant articles and documents
Self-Assembled Multilayer Iron(0) Nanoparticle Catalyst for Ligand-Free Carbon-Carbon/Carbon-Nitrogen Bond-Forming Reactions
Akiyama, Toshiki,Arisawa, Mitsuhiro,Haneoka, Hitoshi,Harada, Kazuo,Hasegawa, Jun-Ya,Honma, Tetsuo,Mashima, Kazushi,Sato, Yoshihiro,Shimoda, Shuhei,Shio, Yasunori,Suzuki, Takeyuki,Tamenori, Yusuke,Tsurugi, Hayato,Tsuruta, Kazuki,Wada, Yuki,Yamada, Makito
, p. 7244 - 7249 (2020/10/12)
Self-assembled multilayer iron(0) nanoparticles (NPs, 6-10 nm), namely, sulfur-modified Au-supported Fe(0) [SAFe(0)], were developed for ligand-free one-pot carbon-carbon/carbon-nitrogen bond-forming reactions. SAFe(0) was successfully prepared using a well-established metal-nanoparticle catalyst preparative protocol by simultaneous in situ metal NP and nanospace organization (PSSO) with 1,4-bis(trimethylsilyl)-1,4-dihydropyrazine (Si-DHP) as a strong reducing agent. SAFe(0) was easy to handle in air and could be recycled with a low iron-leaching rate in reaction cycles.
Synthesis and Properties of New N-Heteroheptacenes for Solution-Based Organic Field Effect Transistors
Zhou, Fei,Liu, Sheng,Santarsiero, Bernard D.,Wink, Donald J.,Boudinet, Damien,Facchetti, Antonio,Driver, Tom
supporting information, p. 12542 - 12549 (2017/09/18)
A series of N-heteroheptacenes was synthesized from ortho-thiophene-substituted aryl azides using a Rh2II-catalyzed C?H bond amination reaction to construct the thienoindole moieties. This reaction tolerated the presence of electron-
Development of a Suzuki cross-coupling reaction between 2-azidoarylboronic pinacolate esters and vinyl triflates to enable the synthesis of [2,3]-fused indole heterocycles
Jana, Navendu,Nguyen, Quyen,Driver, Tom G.
, p. 2781 - 2791 (2014/04/17)
The scope and limitations of a Suzuki reaction between 2-azidoarylboronic acid pinacolate esters and vinyl triflates are reported. This cross-coupling reaction enables the regioselective synthesis of indoles after a subsequent RhII2-catalyzed sp2-C-H bond amination reaction.
