54774-82-2

Basic information

• Product Name: [1-(1-Cyclohexen-1-yl)ethyl]benzene
• Synonyms: [1-(1-Cyclohexen-1-yl)ethyl]benzene
• CAS NO: 54774-82-2
• Molecular Formula: C₁₄H₁₈
• Molecular Weight: 186.29
• Mol File: 54774-82-2.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: [1-(1-Cyclohexen-1-yl)ethyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [1-(1-Cyclohexen-1-yl)ethyl]benzene(54774-82-2)
• EPA Substance Registry System: [1-(1-Cyclohexen-1-yl)ethyl]benzene(54774-82-2)

Safety Data

• Hazardous Substances Data: 54774-82-2(Hazardous Substances Data)

Upstream product

• 94806-21-0 1-Phenyl-1-((1R,2R)-2-tributylstannanyl-cyclohexyl)-ethanol 
• 712-50-5 Cyclohexyl phenyl ketone 
• 74-88-4 methyl iodide 
• 2622-21-1 1-vinylcyclohexene 
• 4406-72-8 2-phenyl[1,3,2]dioxaborolane 
• 1003-64-1 ethylidenecyclohexane 
• 74-85-1 ethene 
• 28075-50-5 cyclohex-1-en-1-yl trifluoromethane sulfonate 
• 98-80-6 phenylboronic acid 
• 931-51-1 cyclohexylmagnesiumchloride 
• 4352-39-0 1-cyclohexyl-1-phenylethanol 
• 98-86-2 acetophenone 

Downstream Products

• 55983-32-9 2-methyl-2-phenylmethylenecyclohexane 
• 4413-16-5 1-ethyl-4-phenylcyclohexane 

Relevant articles and documents

Triphosgene and DMAP as Mild Reagents for Chemoselective Dehydration of Tertiary Alcohols

The utility of triphosgene and DMAP as mild reagents for chemoselective dehydration of tertiary alcohols is reported. Performed in dichloromethane at room temperature, this reaction is readily tolerated by a broad scope of substrates, yielding alkenes preferentially with the (E)-geometry. While formation of the Hofmann products is generally favored, a dramatic change in alkene selectivity toward the Zaitzev products is observed when the reaction is carried out in dichloroethane at reflux.

Copper-catalyzed alkene arylation with diaryliodonium salts

Alkenes and arenes represent two classes of feedstock compounds whose union has fundamental importance to synthetic organic chemistry. We report a new approach to alkene arylation using diaryliodonium salts and Cu catalysis. Using a range of simple alkenes, we have shown that the product outcomes differ significantly from those commonly obtained by the Heck reaction. We have used these insights to develop a number of new tandem and cascade reactions that transform readily available alkenes into complex arylated products that may have broad applications in chemical synthesis.

Aerobic alcohol oxidation coupled to palladium-catalyzed alkene hydroarylation with boronic esters

(Chemical Equation Presented) An oxidation exercise: An aerobic alcohol oxidation coupled with a regioselective palladium-catalyzed reductive functionalization of styrenes and arylboronic esters has been developed (see scheme). The mechanism is thought to proceed by initial oxidation of the solvent to generate a PdII-hydride species, which subsequently reacts with the alkene and arylboronic ester to ultimately generate a new C-C bond.