54852-64-1

Basic information

• Product Name: Benzene, (octyloxy)methyl-
• Synonyms: Benzene, (octyloxy)methyl-;Benzyloctyl ether;Octylbenzyl ether
• CAS NO: 54852-64-1
• Molecular Formula: C₁₅H₂₄O
• Molecular Weight: 220.35
• Mol File: 54852-64-1.mol
• Article Data: 26

Chemical Properties

• Boiling Point: 291.1°C at 760 mmHg
• Flash Point: 137.2°C
• Appearance: /
• Density: 0.902g/cm³
• Vapor Pressure: 0.00346mmHg at 25°C
• Refractive Index: 1.485
• CAS DataBase Reference: Benzene, (octyloxy)methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (octyloxy)methyl-(54852-64-1)
• EPA Substance Registry System: Benzene, (octyloxy)methyl-(54852-64-1)

Safety Data

• Hazardous Substances Data: 54852-64-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 30, p. 4759, 1989 DOI: 10.1016/S0040-4039(01)80501-3Synthesis, p. 803, 1977 DOI: 10.1055/s-1977-24589

InChI:InChI=1/C15H24O/c1-2-3-4-5-6-10-13-16-14-15-11-8-7-9-12-15/h7-9,11-12H,2-6,10,13-14H2,1H3

Upstream product

• 111-87-5 octanol 
• 100-44-7 benzyl chloride 
• 908094-04-2 phenyldiazomethane 
• 24566-90-3 octyl chloromethyl ether 
• 960-16-7 tributylphenylstannane 
• 124-13-0 Octanal 
• 14642-79-6 benzyloxy-trimethylsilane 
• 55791-06-5 benzyl mesylate 
• 111-83-1 1-bromo-octane 
• 100-51-6 benzyl alcohol 
• 1043905-62-9 O-(6-benzyloxy-1-ethyl-hexyl)-S-methyldithiocarbonate 
• 1160063-30-8 1-iodo-2-(octyloxymethyl)benzene 
• 100-52-7 benzaldehyde 
• 108-88-3 toluene 

Downstream Products

• 124-07-2 Octanoic acid 
• 112-14-1 n-octyl acetate 
• 27921-48-8 3-benzylthiophene 
• 13132-15-5 2-benzylthiophene 
• 611-45-0 1-Benzyl-naphthalene 
• 613-59-2 2-benzylnaphthalene 
• 883-90-9 o-benzyl anisole 
• 28122-25-0 1-benzyl-2-ethylbenzene 
• 620-85-9 1-benzyl-4-ethylbenzene 
• 28122-24-9 (3-ethylphenyl)phenylmethane 
• 4453-79-6 2-benzyl-1,3,5-trimethylbenzene 
• 28122-27-2 1-benzyl-3,5-dimethylbenzene 
• 28122-28-3 1-benzyl-2,4-dimethyl-benzene 
• 13540-50-6 2-benzyl-1,4-dimethylbenzene 

Relevant articles and documents

Synthesis of Benzyl Alkyl Ethers by Intermolecular Dehydration of Benzyl Alcohol with Aliphatic Alcohols under the Effect of Copper Containing Catalysts

Synthesis of benzyl alkyl ethers was performed in high yields by intermolecular dehydration of benzyl and primary, secondary, tertiary alcohols under the effect of copper containing catalysts. The formation of benzyl alkyl ethers occurs with participation of benzyl cation.

1-Butyl-3-methylimidazol-2-ylidene Borane: A Readily Available, Liquid N-Heterocyclic Carbene Borane Reagent

1-Butyl-3-methylimidazol-2-ylidene borane has been synthesized directly from two inexpensive commercial reagents: 1-butyl-3-methylimidazolium bromide and sodium borohydride. This NHC-borane reagent is a stable, free-flowing liquid that shows promise for use in radical, ionic, and metal-catalyzed reactions.

Benzylation of arenes with benzyl ethers promoted by the in situ prepared superacid BF3-H2O

An efficient and environmentally friendly benzylation of arenes with benzyl ethers as benzyl donors using BF3-Et2O to generate in situ the superacid BF3-H2O as an efficient promotor has been described. A wide variety of functional groups have been investigated and found to be compatible to give the desired diarylmethanes in yields of up to 99%. The crucial role of the moisture content in this transformation has been demonstrated by detailed investigations. This journal is the Partner Organisations 2014.