55009-92-2

Basic information

• Product Name: (E)-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-en-1-yl)benzene
• CAS NO: 55009-92-2
• Molecular Weight: 422.189
• Mol File: 55009-92-2.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: (E)-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-en-1-yl)benzene(55009-92-2)
• EPA Substance Registry System: (E)-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-en-1-yl)benzene(55009-92-2)

Safety Data

• Hazardous Substances Data: 55009-92-2(Hazardous Substances Data)

Upstream product

• 355-43-1 n-perfluorohexyl iodide 
• 103-64-0 bromostyrene 
• 100-42-5 styrene 
• 55591-23-6 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane-1-sulfonyl chloride 
• 536-74-3 phenylacetylene 
• 355-41-9 perfluoro-n-hexyl chloride 
• 591-50-4 iodobenzene 
• 1374104-95-6 1,3-bis(1-iodo-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctan-1-yl)tetramethyldisiloxane 
• 25291-17-2 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene 
• 108-86-1 bromobenzene 
• 42599-24-6 E-styryl iodide 
• 101349-79-5 2-phenylvinyl iodide 
• 335-56-8 1-bromo-1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane 
• 140-10-3 (E)-3-phenylacrylic acid 

Relevant articles and documents

Fluoroalkenylation of boronic acids: Via an oxidative Heck reaction

A fluoroalkenylation of boronic acids with fluoroalkyl alkenes has been developed. The Pd-catalyzed oxidative Heck coupling reaction proceeds under an oxygen atmosphere at room temperature, in the absence of a base and/or a ligand, showing excellent practicality of the process. This simple transformation is highly stereoselective to provide only E-isomers. In addition to the general approach using alkenes with functionalized fluoroalkyl reagents, this method, by transferring an aromatic system to the electron-deficient fluoroalkyl alkene, provides an efficient alternative method to yield valuable organofluorines.

METHOD FOR PRODUCING FLUORINE-CONTAINING OLEFIN

PROBLEM TO BE SOLVED: To provide a method for simply and efficiently producing a fluorine-containing olefin having a perfluoro-alkyl group under a mild condition. SOLUTION: Provided is a method for producing a compound represented by the following formula (51) by reacting a compound represented by the following formula (21) and a compound represented by the following formula (31) under the presence of a metal-carbene complex compound (10) having an olefin metathesis reaction activity. SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT

A general synthesis of fluoroalkylated alkenes by palladium-catalyzed Heck-type reaction of fluoroalkyl bromides

An efficient palladium-catalyzed Heck-type reaction of fluoroalkyl halides, including perfluoroalkyl bromides, trifluoromethyl iodides, and difluoroalkyl bromides, has been developed. The reaction proceeds under mild reaction conditions with high efficiency and broad substrate scope, and provides a general and straightforward access to fluoroalkylated alkenes which are of interest in life and material sciences.