55277-95-7

Upstream product

• 76-39-1 2-nitro-2-methylpropanol 
• 100-52-7 benzaldehyde 
• 4706-13-2 N-(1-hydroxy-2-methylprop-2-yl)-hydroxylamine 
• 22563-90-2 2-Benzalamino-isobutanol 

Downstream Products

• 63829-78-7 2-(Hydroxylamino)-2-methylpropyl benzoate 
• 160423-64-3 2-(N-benzyl-N-hydroxyamino)-2-dimethylpropanol 
• 293328-26-4 C₁₇H₂₉NO₂Si 
• 63829-74-3 4,4-dimethyl-3-(4-nitro-benzoyloxy)-2-phenyl-oxazolidine 
• 63829-81-2 3-acetoxy-4,4-dimethyl-2-phenyl-oxazolidine 
• 1005001-05-7 2,2-dimethyl-2-[(phenylmethylene)amino] N-oxide succinimidyl carbonate 
• 63829-80-1 C₁₈H₁₉NO₃ 
• 270901-81-0 N-(1,1-dimethyl-2-[tert-butyldimethylsilanyloxy]propyl)-N-(2-methyl-1-phenylpropyl)-N-oxyl 
• 293328-27-5 N-(1,1-dimethyl-2-hydroxypropyl)-N-(2-methyl-1-phenylpropyl)-N-oxyl 
• 913816-71-4 2-succinimidyloxycarbonyloxy-1,1-dimethylethyl 2-methyl-1-phenylpropyl nitroxide 
• 393110-72-0 N-[2-(tert-butyl-dimethyl-silanyloxy)-1,1-dimethyl-ethyl]-N-(2-methyl-1-phenyl-propyl)-hydroxylamine 

Relevant academic research and scientific papers

Reactivities of substituted α-phenyl-N-tert-butyl nitrones

In this work, a series of α-phenyl-N-tert-butyl nitrones bearing one, two, or three substituents on the tert-butyl group was synthesized. Cyclic voltammetry (CV) was used to investigate their electrochemical properties and showed a more pronounced substit

Nitroxide bound β-cyclodextrin: Is there an inclusion complex?

(Figure Presented) 236CDTIPNO, a derivative of the persistent free radical TIPNO (1,1-dimethylethyl 2-methyl-1-phenylpropyl nitroxide) covalently bound to a permethylated-β-cyclodextrin, was prepared. Self-association of 236CDTIPNO in water was proved by

Theoretical determination of the standard reduction potential of plastocyanin in vitro

The determination of the reduction potential of the protein plastocyanin was discussed using quantum chemical QM/MM calculations. Protein was divided into smaller parts using ONIOM method and it was based on its relative contribution to reduction potentia

Bicyclic and tricyclic compounds with β-amino alcohol groups as chiral ligands in the enantioselective reaction of diethylzinc with aldehydes

Reduction of the enantiomerically pure allyloxy esters 9 or ent-9 with DIBAH afforded the corresponding aldehydes which were treated in situ with chiral or achiral hydroxylamines 8 to give nitrones 10. These underwent a spontaneous intramolecular 1,3-dipolar cycloaddition, affording the bicyclic compounds 11 and 12, respectively. In an analogous manner, a mixture of the tricyclic compounds 14 and 15 was prepared. Treatment of compound 16 with cyclohexene oxide afforded a mixture of diastereomers 17 and 18. Diastereomers 14 and 15 as well as 17 and 18 could be separated by chromatography. X-ray analyses of compounds 11Ff, 17, and 11Af · HCI were performed. The bicyclic and tricyclic compounds were used as chiral ligands in the reaction of diethylzinc with aldehydes 19, in particular with benzaldehyde (19a). Using bicyclic compounds with a tertiary β-hydroxyalkyl substituent at the N atom as ligands, ee's in the range of 78 to 95% were found. Whereas for the best ligands 11Ae and Af the enantioselectivity in the reaction of 4-tolualdehyde was only slightly decreased, with the aliphatic aldehydes 19c and d distinctly lower enantioselectivities were determined. VCH Verlagsgesellschaft mbH, 1997.